Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate

The central Ag(I) atom of the title salt, [Ag(INAM)(2)](CF(3)SO(3))·2CH(3)CN, where INAM is isonicotinamide (C(6)H(6)N(2)O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol­ecular geometry. The formation of polymeric chains {[Ag(...

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Detalles Bibliográficos
Autores principales: Adrian, Rafael A., Ibarra, Sara J., Arman, Hadi D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462304/
https://www.ncbi.nlm.nih.gov/pubmed/36340985
http://dx.doi.org/10.1107/S2414314621010737
Descripción
Sumario:The central Ag(I) atom of the title salt, [Ag(INAM)(2)](CF(3)SO(3))·2CH(3)CN, where INAM is isonicotinamide (C(6)H(6)N(2)O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol­ecular geometry. The formation of polymeric chains {[Ag(INAM)(2)](+)}( n ), held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto­nitrile mol­ecules that inter­act the silver metal center via regium bonds. [Image: see text]

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