Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate

The central Ag(I) atom of the title salt, [Ag(INAM)(2)](CF(3)SO(3))·2CH(3)CN, where INAM is isonicotinamide (C(6)H(6)N(2)O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol­ecular geometry. The formation of polymeric chains {[Ag(...

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Detalles Bibliográficos
Autores principales: Adrian, Rafael A., Ibarra, Sara J., Arman, Hadi D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462304/
https://www.ncbi.nlm.nih.gov/pubmed/36340985
http://dx.doi.org/10.1107/S2414314621010737
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author Adrian, Rafael A.
Ibarra, Sara J.
Arman, Hadi D.
author_facet Adrian, Rafael A.
Ibarra, Sara J.
Arman, Hadi D.
author_sort Adrian, Rafael A.
collection PubMed
description The central Ag(I) atom of the title salt, [Ag(INAM)(2)](CF(3)SO(3))·2CH(3)CN, where INAM is isonicotinamide (C(6)H(6)N(2)O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol­ecular geometry. The formation of polymeric chains {[Ag(INAM)(2)](+)}( n ), held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto­nitrile mol­ecules that inter­act the silver metal center via regium bonds. [Image: see text]
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spelling pubmed-94623042022-11-04 Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate Adrian, Rafael A. Ibarra, Sara J. Arman, Hadi D. IUCrdata Data Reports The central Ag(I) atom of the title salt, [Ag(INAM)(2)](CF(3)SO(3))·2CH(3)CN, where INAM is isonicotinamide (C(6)H(6)N(2)O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol­ecular geometry. The formation of polymeric chains {[Ag(INAM)(2)](+)}( n ), held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto­nitrile mol­ecules that inter­act the silver metal center via regium bonds. [Image: see text] International Union of Crystallography 2021-10-21 /pmc/articles/PMC9462304/ /pubmed/36340985 http://dx.doi.org/10.1107/S2414314621010737 Text en © Adrian et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Adrian, Rafael A.
Ibarra, Sara J.
Arman, Hadi D.
Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
title Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
title_full Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
title_fullStr Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
title_full_unstemmed Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
title_short Bis(isonicotinamide-κN)silver(I) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
title_sort bis(isonicotinamide-κn)silver(i) tri­fluoro­methane­sulfonate aceto­nitrile disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462304/
https://www.ncbi.nlm.nih.gov/pubmed/36340985
http://dx.doi.org/10.1107/S2414314621010737
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AT ibarrasaraj bisisonicotinamideknsilveritrifluoromethanesulfonateacetonitriledisolvate
AT armanhadid bisisonicotinamideknsilveritrifluoromethanesulfonateacetonitriledisolvate

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