Methyl α-l-sorboside monohydrate

Methyl l-sorboside monohydrate, C(7)H(14)O(6)·H(2)O, was prepared from the rare sugar l-sorbose, C(6)H(12)O(6), and crystallized. It was confirmed that methyl l-sorboside formed α-pyran­ose with a (2) C (5) conformation and crystallized with one water molecule of crystallization. In the crystal, mol...

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Autores principales: Matsumoto, Mao, Nagayama, Natsumi, Hirose, Ryo, Takeshita, Kei, Ishii, Tomohiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462306/
https://www.ncbi.nlm.nih.gov/pubmed/36337594
http://dx.doi.org/10.1107/S2414314621013250
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author Matsumoto, Mao
Nagayama, Natsumi
Hirose, Ryo
Takeshita, Kei
Ishii, Tomohiko
author_facet Matsumoto, Mao
Nagayama, Natsumi
Hirose, Ryo
Takeshita, Kei
Ishii, Tomohiko
author_sort Matsumoto, Mao
collection PubMed
description Methyl l-sorboside monohydrate, C(7)H(14)O(6)·H(2)O, was prepared from the rare sugar l-sorbose, C(6)H(12)O(6), and crystallized. It was confirmed that methyl l-sorboside formed α-pyran­ose with a (2) C (5) conformation and crystallized with one water molecule of crystallization. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title compound, methyl l-sorboside monohydrate, is 481.13 (2) Å(3) (Z = 2), which is about 108.16 Å(3) (29.0%) greater than that of half the amount of the chemical α-l-sorbose [745.94 (2) Å(3) (Z = 4)]. [Image: see text]
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spelling pubmed-94623062022-11-04 Methyl α-l-sorboside monohydrate Matsumoto, Mao Nagayama, Natsumi Hirose, Ryo Takeshita, Kei Ishii, Tomohiko IUCrdata Data Reports Methyl l-sorboside monohydrate, C(7)H(14)O(6)·H(2)O, was prepared from the rare sugar l-sorbose, C(6)H(12)O(6), and crystallized. It was confirmed that methyl l-sorboside formed α-pyran­ose with a (2) C (5) conformation and crystallized with one water molecule of crystallization. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title compound, methyl l-sorboside monohydrate, is 481.13 (2) Å(3) (Z = 2), which is about 108.16 Å(3) (29.0%) greater than that of half the amount of the chemical α-l-sorbose [745.94 (2) Å(3) (Z = 4)]. [Image: see text] International Union of Crystallography 2021-12-21 /pmc/articles/PMC9462306/ /pubmed/36337594 http://dx.doi.org/10.1107/S2414314621013250 Text en © Matsumoto et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Matsumoto, Mao
Nagayama, Natsumi
Hirose, Ryo
Takeshita, Kei
Ishii, Tomohiko
Methyl α-l-sorboside monohydrate
title Methyl α-l-sorboside monohydrate
title_full Methyl α-l-sorboside monohydrate
title_fullStr Methyl α-l-sorboside monohydrate
title_full_unstemmed Methyl α-l-sorboside monohydrate
title_short Methyl α-l-sorboside monohydrate
title_sort methyl α-l-sorboside monohydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462306/
https://www.ncbi.nlm.nih.gov/pubmed/36337594
http://dx.doi.org/10.1107/S2414314621013250
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AT nagayamanatsumi methylalsorbosidemonohydrate
AT hiroseryo methylalsorbosidemonohydrate
AT takeshitakei methylalsorbosidemonohydrate
AT ishiitomohiko methylalsorbosidemonohydrate

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