Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)

The title compound, [RuCl(2)(C(10)H(14))(C(21)H(21)O(3)P)], crystallizes with two complex mol­ecules in the asymmetric unit. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru—centroid = 1.707 (2)/1.704 (2) Å], a tris­(4-meth­oxy­phen­yl)pho...

Descripción completa

Detalles Bibliográficos
Autores principales: Davis, Wade L., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462307/
https://www.ncbi.nlm.nih.gov/pubmed/36337593
http://dx.doi.org/10.1107/S2414314621012591
Descripción
Sumario:The title compound, [RuCl(2)(C(10)H(14))(C(21)H(21)O(3)P)], crystallizes with two complex mol­ecules in the asymmetric unit. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru—centroid = 1.707 (2)/1.704 (2) Å], a tris­(4-meth­oxy­phen­yl)phosphane ligand [Ru—P = 2.3629 (15)/2.3665 (15) Å] and two chloride atoms with the Ru—Cl bonds adopting two distinct values of 2.4068 (16)/2.4167 (16) and 2.4016 (15)/2.4244 (16) Å. The effective cone and solid angles for the phosphane ligands were calculated to be 149.5/150.2° and 25.3/25.6°, respectively. In the crystal, weak C—H⋯Cl/O/π inter­actions are observed. The crystal was refined as a two-component twin. [Image: see text]

Ejemplares similares