Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)

The title compound, [RuCl(2)(C(10)H(14))(C(21)H(21)O(3)P)], crystallizes with two complex mol­ecules in the asymmetric unit. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru—centroid = 1.707 (2)/1.704 (2) Å], a tris­(4-meth­oxy­phen­yl)pho...

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Autores principales: Davis, Wade L., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462307/
https://www.ncbi.nlm.nih.gov/pubmed/36337593
http://dx.doi.org/10.1107/S2414314621012591
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author Davis, Wade L.
Muller, Alfred
author_facet Davis, Wade L.
Muller, Alfred
author_sort Davis, Wade L.
collection PubMed
description The title compound, [RuCl(2)(C(10)H(14))(C(21)H(21)O(3)P)], crystallizes with two complex mol­ecules in the asymmetric unit. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru—centroid = 1.707 (2)/1.704 (2) Å], a tris­(4-meth­oxy­phen­yl)phosphane ligand [Ru—P = 2.3629 (15)/2.3665 (15) Å] and two chloride atoms with the Ru—Cl bonds adopting two distinct values of 2.4068 (16)/2.4167 (16) and 2.4016 (15)/2.4244 (16) Å. The effective cone and solid angles for the phosphane ligands were calculated to be 149.5/150.2° and 25.3/25.6°, respectively. In the crystal, weak C—H⋯Cl/O/π inter­actions are observed. The crystal was refined as a two-component twin. [Image: see text]
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spelling pubmed-94623072022-11-04 Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II) Davis, Wade L. Muller, Alfred IUCrdata Data Reports The title compound, [RuCl(2)(C(10)H(14))(C(21)H(21)O(3)P)], crystallizes with two complex mol­ecules in the asymmetric unit. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru—centroid = 1.707 (2)/1.704 (2) Å], a tris­(4-meth­oxy­phen­yl)phosphane ligand [Ru—P = 2.3629 (15)/2.3665 (15) Å] and two chloride atoms with the Ru—Cl bonds adopting two distinct values of 2.4068 (16)/2.4167 (16) and 2.4016 (15)/2.4244 (16) Å. The effective cone and solid angles for the phosphane ligands were calculated to be 149.5/150.2° and 25.3/25.6°, respectively. In the crystal, weak C—H⋯Cl/O/π inter­actions are observed. The crystal was refined as a two-component twin. [Image: see text] International Union of Crystallography 2021-12-02 /pmc/articles/PMC9462307/ /pubmed/36337593 http://dx.doi.org/10.1107/S2414314621012591 Text en © Davis and Muller 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Davis, Wade L.
Muller, Alfred
Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)
title Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)
title_full Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)
title_fullStr Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)
title_full_unstemmed Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)
title_short Di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II)
title_sort di­chlorido­(η(6)-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462307/
https://www.ncbi.nlm.nih.gov/pubmed/36337593
http://dx.doi.org/10.1107/S2414314621012591
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AT mulleralfred dichloridoē6pcymenetris4methoxyphenylphosphanerutheniumii

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