rac-(2aS,2a(1) R,3aR,3a(1) S,5aS,6aR)-2a-Allyl-2,4-di­chloro-2a,2a(1),3a(1),5a,6,6a-hexa­hydro-3aH-3-oxadi­cyclo­penta­[cd,gh]penta­len-3a-ol

The title racemic triquinane, C(14)H(14)Cl(2)O(2), is composed of four five-membered rings, one of which is a tetra­hydro­furan ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crysta...

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Detalles Bibliográficos
Autores principales: Kotha, Sambasivarao, Ansari, Saima, Gupta, Naveen Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462309/
https://www.ncbi.nlm.nih.gov/pubmed/36337590
http://dx.doi.org/10.1107/S2414314621012608
Descripción
Sumario:The title racemic triquinane, C(14)H(14)Cl(2)O(2), is composed of four five-membered rings, one of which is a tetra­hydro­furan ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crystal, the mol­ecules are linked by pairwise O—H⋯O hydrogen bonds, generating inversion dimers featuring R (2) (2)(8) loops. [Image: see text]

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