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rac-(2aS,2a(1) R,3aR,3a(1) S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol
The title racemic triquinane, C(14)H(14)Cl(2)O(2), is composed of four five-membered rings, one of which is a tetrahydrofuran ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crysta...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462309/ https://www.ncbi.nlm.nih.gov/pubmed/36337590 http://dx.doi.org/10.1107/S2414314621012608 |
| _version_ | 1784787157047574528 |
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| author | Kotha, Sambasivarao Ansari, Saima Gupta, Naveen Kumar |
| author_facet | Kotha, Sambasivarao Ansari, Saima Gupta, Naveen Kumar |
| author_sort | Kotha, Sambasivarao |
| collection | PubMed |
| description | The title racemic triquinane, C(14)H(14)Cl(2)O(2), is composed of four five-membered rings, one of which is a tetrahydrofuran ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crystal, the molecules are linked by pairwise O—H⋯O hydrogen bonds, generating inversion dimers featuring R (2) (2)(8) loops. [Image: see text] |
| format | Online Article Text |
| id | pubmed-9462309 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-94623092022-11-04 rac-(2aS,2a(1) R,3aR,3a(1) S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol Kotha, Sambasivarao Ansari, Saima Gupta, Naveen Kumar IUCrdata Data Reports The title racemic triquinane, C(14)H(14)Cl(2)O(2), is composed of four five-membered rings, one of which is a tetrahydrofuran ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crystal, the molecules are linked by pairwise O—H⋯O hydrogen bonds, generating inversion dimers featuring R (2) (2)(8) loops. [Image: see text] International Union of Crystallography 2021-12-16 /pmc/articles/PMC9462309/ /pubmed/36337590 http://dx.doi.org/10.1107/S2414314621012608 Text en © Kotha et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Kotha, Sambasivarao Ansari, Saima Gupta, Naveen Kumar rac-(2aS,2a(1) R,3aR,3a(1) S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| title |
rac-(2aS,2a(1)
R,3aR,3a(1)
S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| title_full |
rac-(2aS,2a(1)
R,3aR,3a(1)
S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| title_fullStr |
rac-(2aS,2a(1)
R,3aR,3a(1)
S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| title_full_unstemmed |
rac-(2aS,2a(1)
R,3aR,3a(1)
S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| title_short |
rac-(2aS,2a(1)
R,3aR,3a(1)
S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| title_sort | rac-(2as,2a(1)
r,3ar,3a(1)
s,5as,6ar)-2a-allyl-2,4-dichloro-2a,2a(1),3a(1),5a,6,6a-hexahydro-3ah-3-oxadicyclopenta[cd,gh]pentalen-3a-ol |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462309/ https://www.ncbi.nlm.nih.gov/pubmed/36337590 http://dx.doi.org/10.1107/S2414314621012608 |
| work_keys_str_mv | AT kothasambasivarao rac2as2a1r3ar3a1s5as6ar2aallyl24dichloro2a2a13a15a66ahexahydro3ah3oxadicyclopentacdghpentalen3aol AT ansarisaima rac2as2a1r3ar3a1s5as6ar2aallyl24dichloro2a2a13a15a66ahexahydro3ah3oxadicyclopentacdghpentalen3aol AT guptanaveenkumar rac2as2a1r3ar3a1s5as6ar2aallyl24dichloro2a2a13a15a66ahexahydro3ah3oxadicyclopentacdghpentalen3aol |