Cargando…

13-Benzyl-4,11-dihy­droxy-1,8-diphen­yl-2,9-di­thia-13-aza­dispiro­[4.1.4.3]tetra­decan-6-one

In the title compound, C(30)H(31)NO(3)S(2), the piperidine ring adopts a distorted chair conformation. The thio­phene rings have twisted conformations about the C—C bonds. The mean plane of the piperidine ring makes a near orthogonal conformation with the toluene ring. Two of the phenyl rings in the...

Descripción completa

Detalles Bibliográficos
Autores principales: Vinotha, G., Sundar, T. V., Sharmila, N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462310/
https://www.ncbi.nlm.nih.gov/pubmed/36338860
http://dx.doi.org/10.1107/S2414314621002108
Descripción
Sumario:In the title compound, C(30)H(31)NO(3)S(2), the piperidine ring adopts a distorted chair conformation. The thio­phene rings have twisted conformations about the C—C bonds. The mean plane of the piperidine ring makes a near orthogonal conformation with the toluene ring. Two of the phenyl rings in the structure are positionally disordered over two sets of sites with occupancies of 0.56 (2)/0.44 (2) and 0.672 (16)/0.328 (16). A region of disordered electron density was corrected for using the SQUEEZE [Spek (2015 ▸). Acta Cryst. C71, 9–18] routine in PLATON. The given chemical formula and other crystal data do not take into account the unknown solvent mol­ecule. In the crystal, O—H⋯O hydrogen bonds are observed along with intra­molecular S⋯H, O⋯H, C⋯H and H⋯H contacts. [Image: see text]