Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate

The title solvated bimetallic complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·C(2)H(5)OH, comprises two Cd(2+) metal ions linked by a pair of μ(2) Cl(−) ions. The coordination sphere around each Cd(2+) ion is completed by three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]quinoline ligand and...

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Detalles Bibliográficos
Autores principales: Al-Sudani, Abdul-Razak H., Abdulridha, Myasim Qasim, Kariuki, Benson M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462312/
https://www.ncbi.nlm.nih.gov/pubmed/36338861
http://dx.doi.org/10.1107/S2414314621001504
Descripción
Sumario:The title solvated bimetallic complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·C(2)H(5)OH, comprises two Cd(2+) metal ions linked by a pair of μ(2) Cl(−) ions. The coordination sphere around each Cd(2+) ion is completed by three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]quinoline ligand and another chloride ion to form a distorted fac-CdN(3)Cl(3) octa­hedron. The ethanol mol­ecule is both an acceptor of an N—H⋯O and a donor of an O—H⋯Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed. [Image: see text]

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