Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate

The title solvated bimetallic complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·C(2)H(5)OH, comprises two Cd(2+) metal ions linked by a pair of μ(2) Cl(−) ions. The coordination sphere around each Cd(2+) ion is completed by three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]quinoline ligand and...

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Autores principales: Al-Sudani, Abdul-Razak H., Abdulridha, Myasim Qasim, Kariuki, Benson M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462312/
https://www.ncbi.nlm.nih.gov/pubmed/36338861
http://dx.doi.org/10.1107/S2414314621001504
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author Al-Sudani, Abdul-Razak H.
Abdulridha, Myasim Qasim
Kariuki, Benson M.
author_facet Al-Sudani, Abdul-Razak H.
Abdulridha, Myasim Qasim
Kariuki, Benson M.
author_sort Al-Sudani, Abdul-Razak H.
collection PubMed
description The title solvated bimetallic complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·C(2)H(5)OH, comprises two Cd(2+) metal ions linked by a pair of μ(2) Cl(−) ions. The coordination sphere around each Cd(2+) ion is completed by three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]quinoline ligand and another chloride ion to form a distorted fac-CdN(3)Cl(3) octa­hedron. The ethanol mol­ecule is both an acceptor of an N—H⋯O and a donor of an O—H⋯Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed. [Image: see text]
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spelling pubmed-94623122022-11-04 Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate Al-Sudani, Abdul-Razak H. Abdulridha, Myasim Qasim Kariuki, Benson M. IUCrdata Data Reports The title solvated bimetallic complex, [Cd(2)Cl(4)(C(13)H(17)N(3))(2)]·C(2)H(5)OH, comprises two Cd(2+) metal ions linked by a pair of μ(2) Cl(−) ions. The coordination sphere around each Cd(2+) ion is completed by three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]quinoline ligand and another chloride ion to form a distorted fac-CdN(3)Cl(3) octa­hedron. The ethanol mol­ecule is both an acceptor of an N—H⋯O and a donor of an O—H⋯Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed. [Image: see text] International Union of Crystallography 2021-02-16 /pmc/articles/PMC9462312/ /pubmed/36338861 http://dx.doi.org/10.1107/S2414314621001504 Text en © Al-Sudani et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Al-Sudani, Abdul-Razak H.
Abdulridha, Myasim Qasim
Kariuki, Benson M.
Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
title Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
title_full Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
title_fullStr Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
title_full_unstemmed Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
title_short Di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
title_sort di-μ-chlorido-bis­(chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline}­cadmium) ethanol monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462312/
https://www.ncbi.nlm.nih.gov/pubmed/36338861
http://dx.doi.org/10.1107/S2414314621001504
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AT abdulridhamyasimqasim dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate
AT kariukibensonm dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate

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