Cargando…
Dichlorido(pyridine-κN)[2,3,5,6-tetrakis(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
In the title complex, [NiCl(2)(C(5)H(5)N)(C(24)H(16)N(6))], the Ni(II) ion is six-coordinated in a distorted octahedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine ligand, one N atom of the pyridine ligand and two Cl(−) anions, with the latte...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462313/ https://www.ncbi.nlm.nih.gov/pubmed/36338856 http://dx.doi.org/10.1107/S2414314621000948 |
Sumario: | In the title complex, [NiCl(2)(C(5)H(5)N)(C(24)H(16)N(6))], the Ni(II) ion is six-coordinated in a distorted octahedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine ligand, one N atom of the pyridine ligand and two Cl(−) anions, with the latter being mutually trans. The complex is disposed about a twofold rotation axis along the a axis. The complex molecules are connected in the crystal via C—H⋯Cl, C—H⋯N and π–π [closest inter-centroid separation = 3.7446 (14) Å between pyridyl rings]. [Image: see text] |
---|