Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)

In the title complex, [NiCl(2)(C(5)H(5)N)(C(24)H(16)N(6))], the Ni(II) ion is six-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligand, one N atom of the pyridine ligand and two Cl(−) anions, with the latte...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462313/
https://www.ncbi.nlm.nih.gov/pubmed/36338856
http://dx.doi.org/10.1107/S2414314621000948
_version_ 1784787158016458752
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [NiCl(2)(C(5)H(5)N)(C(24)H(16)N(6))], the Ni(II) ion is six-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligand, one N atom of the pyridine ligand and two Cl(−) anions, with the latter being mutually trans. The complex is disposed about a twofold rotation axis along the a axis. The complex molecules are connected in the crystal via C—H⋯Cl, C—H⋯N and π–π [closest inter-centroid separation = 3.7446 (14) Å between pyridyl rings]. [Image: see text]
format Online
Article
Text
id pubmed-9462313
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94623132022-11-04 Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II) Ha, Kwang IUCrdata Data Reports In the title complex, [NiCl(2)(C(5)H(5)N)(C(24)H(16)N(6))], the Ni(II) ion is six-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine ligand, one N atom of the pyridine ligand and two Cl(−) anions, with the latter being mutually trans. The complex is disposed about a twofold rotation axis along the a axis. The complex molecules are connected in the crystal via C—H⋯Cl, C—H⋯N and π–π [closest inter-centroid separation = 3.7446 (14) Å between pyridyl rings]. [Image: see text] International Union of Crystallography 2021-02-02 /pmc/articles/PMC9462313/ /pubmed/36338856 http://dx.doi.org/10.1107/S2414314621000948 Text en © Kwang Ha 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ha, Kwang
Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
title Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
title_full Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
title_fullStr Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
title_full_unstemmed Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
title_short Di­chlorido­(pyridine-κN)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) N (2),N (1),N (6)]nickel(II)
title_sort di­chlorido­(pyridine-κn)[2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine-κ(3) n (2),n (1),n (6)]nickel(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462313/
https://www.ncbi.nlm.nih.gov/pubmed/36338856
http://dx.doi.org/10.1107/S2414314621000948
work_keys_str_mv AT hakwang dichloridopyridinekn2356tetrakispyridin2ylpyrazinek3n2n1n6nickelii

Ejemplares similares