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9-[(Z)-2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)ethenyl]-9H-carbazole
The title compound, C(20)H(22)BNO(2), has a polarized π-system due to resonance between N—C(H)=C(H)—B and ionic N(+)=C(H)—C(H)=B(−) canonical structures. The dihedral angles between the ethenyl plane (r.m.s. deviation for C(2)H(2) = 0.0333 Å) with the ethenyl-C(NC(2)-pyrrole) plane (r.m.s. deviation...
Autores principales: | Kanagawa, Mayu, Akagi, Kazuto, Okuno, Tsunehisa |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462315/ https://www.ncbi.nlm.nih.gov/pubmed/36338862 http://dx.doi.org/10.1107/S2414314621001425 |
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