Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate

There are two main molecules in asymmetric unit of the title compound, C(27)H(21)N(3)O(6)·0.5C(2)H(5)OH. In both, the indole ring systems are approximately perpendicular to each other, at dihedral angles of 69.3 (5) and 82.8(4)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bond...

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Autores principales: Li, Yu-Long, Zhou, Jin, Jiang, Hong, Sun, Hong-Shun, Li, Rui-Zhe, Liu, Sha-Li, Zhang, Xu-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462316/
https://www.ncbi.nlm.nih.gov/pubmed/36338863
http://dx.doi.org/10.1107/S2414314621000572
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author Li, Yu-Long
Zhou, Jin
Jiang, Hong
Sun, Hong-Shun
Li, Rui-Zhe
Liu, Sha-Li
Zhang, Xu-Dong
author_facet Li, Yu-Long
Zhou, Jin
Jiang, Hong
Sun, Hong-Shun
Li, Rui-Zhe
Liu, Sha-Li
Zhang, Xu-Dong
author_sort Li, Yu-Long
collection PubMed
description There are two main molecules in asymmetric unit of the title compound, C(27)H(21)N(3)O(6)·0.5C(2)H(5)OH. In both, the indole ring systems are approximately perpendicular to each other, at dihedral angles of 69.3 (5) and 82.8(4)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional supra­molecular architecture. The solvent ethanol mol­ecule acts as a donor, forming an O—H⋯O hydrogen bond, reinforcing the structure. [Image: see text]
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spelling pubmed-94623162022-11-04 Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate Li, Yu-Long Zhou, Jin Jiang, Hong Sun, Hong-Shun Li, Rui-Zhe Liu, Sha-Li Zhang, Xu-Dong IUCrdata Data Reports There are two main molecules in asymmetric unit of the title compound, C(27)H(21)N(3)O(6)·0.5C(2)H(5)OH. In both, the indole ring systems are approximately perpendicular to each other, at dihedral angles of 69.3 (5) and 82.8(4)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional supra­molecular architecture. The solvent ethanol mol­ecule acts as a donor, forming an O—H⋯O hydrogen bond, reinforcing the structure. [Image: see text] International Union of Crystallography 2021-01-26 /pmc/articles/PMC9462316/ /pubmed/36338863 http://dx.doi.org/10.1107/S2414314621000572 Text en © Li et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Li, Yu-Long
Zhou, Jin
Jiang, Hong
Sun, Hong-Shun
Li, Rui-Zhe
Liu, Sha-Li
Zhang, Xu-Dong
Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate
title Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate
title_full Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate
title_fullStr Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate
title_full_unstemmed Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate
title_short Dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol hemisolvate
title_sort dimethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1h-indole-2-carboxyl­ate) ethanol hemisolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462316/
https://www.ncbi.nlm.nih.gov/pubmed/36338863
http://dx.doi.org/10.1107/S2414314621000572
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