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Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate acetonitrile monosolvate
The title compound, [Pd(C(14)H(10)N(4))(2)](NO(3))(2)·CH(3)CN, consists of a cationic Pd(II) complex, two anions and one lattice solvent molecule, all in general positions. In the complex, the Pd(II) cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N ato...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462318/ https://www.ncbi.nlm.nih.gov/pubmed/36338858 http://dx.doi.org/10.1107/S241431462100153X |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The title compound, [Pd(C(14)H(10)N(4))(2)](NO(3))(2)·CH(3)CN, consists of a cationic Pd(II) complex, two anions and one lattice solvent molecule, all in general positions. In the complex, the Pd(II) cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate 2,3-di-2-pyridylpyrazine ligands. The complex, anions and solvent molecule are linked by weak C—H⋯O intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis. [Image: see text] |
format | Online Article Text |
id | pubmed-9462318 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94623182022-11-04 Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate acetonitrile monosolvate Ha, Kwang IUCrdata Data Reports The title compound, [Pd(C(14)H(10)N(4))(2)](NO(3))(2)·CH(3)CN, consists of a cationic Pd(II) complex, two anions and one lattice solvent molecule, all in general positions. In the complex, the Pd(II) cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate 2,3-di-2-pyridylpyrazine ligands. The complex, anions and solvent molecule are linked by weak C—H⋯O intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis. [Image: see text] International Union of Crystallography 2021-02-12 /pmc/articles/PMC9462318/ /pubmed/36338858 http://dx.doi.org/10.1107/S241431462100153X Text en © Kwang Ha 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Ha, Kwang Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate acetonitrile monosolvate |
title | Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2)
N
(2),N
(3)]palladium(II) dinitrate acetonitrile monosolvate |
title_full | Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2)
N
(2),N
(3)]palladium(II) dinitrate acetonitrile monosolvate |
title_fullStr | Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2)
N
(2),N
(3)]palladium(II) dinitrate acetonitrile monosolvate |
title_full_unstemmed | Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2)
N
(2),N
(3)]palladium(II) dinitrate acetonitrile monosolvate |
title_short | Bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2)
N
(2),N
(3)]palladium(II) dinitrate acetonitrile monosolvate |
title_sort | bis[2,3-bis(pyridin-2-yl)pyrazine-κ(2)
n
(2),n
(3)]palladium(ii) dinitrate acetonitrile monosolvate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462318/ https://www.ncbi.nlm.nih.gov/pubmed/36338858 http://dx.doi.org/10.1107/S241431462100153X |
work_keys_str_mv | AT hakwang bis23bispyridin2ylpyrazinek2n2n3palladiumiidinitrateacetonitrilemonosolvate |