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Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate

The title compound, [Pd(C(14)H(10)N(4))(2)](NO(3))(2)·CH(3)CN, consists of a cationic Pd(II) complex, two anions and one lattice solvent mol­ecule, all in general positions. In the complex, the Pd(II) cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N ato...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462318/
https://www.ncbi.nlm.nih.gov/pubmed/36338858
http://dx.doi.org/10.1107/S241431462100153X
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The title compound, [Pd(C(14)H(10)N(4))(2)](NO(3))(2)·CH(3)CN, consists of a cationic Pd(II) complex, two anions and one lattice solvent mol­ecule, all in general positions. In the complex, the Pd(II) cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate 2,3-di-2-pyridyl­pyrazine ligands. The complex, anions and solvent mol­ecule are linked by weak C—H⋯O inter­molecular hydrogen bonds. In the crystal, the complex mol­ecules are stacked in columns along the a axis. [Image: see text]
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spelling pubmed-94623182022-11-04 Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate Ha, Kwang IUCrdata Data Reports The title compound, [Pd(C(14)H(10)N(4))(2)](NO(3))(2)·CH(3)CN, consists of a cationic Pd(II) complex, two anions and one lattice solvent mol­ecule, all in general positions. In the complex, the Pd(II) cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate 2,3-di-2-pyridyl­pyrazine ligands. The complex, anions and solvent mol­ecule are linked by weak C—H⋯O inter­molecular hydrogen bonds. In the crystal, the complex mol­ecules are stacked in columns along the a axis. [Image: see text] International Union of Crystallography 2021-02-12 /pmc/articles/PMC9462318/ /pubmed/36338858 http://dx.doi.org/10.1107/S241431462100153X Text en © Kwang Ha 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ha, Kwang
Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate
title Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate
title_full Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate
title_fullStr Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate
title_full_unstemmed Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate
title_short Bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) N (2),N (3)]palladium(II) dinitrate aceto­nitrile monosolvate
title_sort bis[2,3-bis­(pyridin-2-yl)pyrazine-κ(2) n (2),n (3)]palladium(ii) dinitrate aceto­nitrile monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462318/
https://www.ncbi.nlm.nih.gov/pubmed/36338858
http://dx.doi.org/10.1107/S241431462100153X
work_keys_str_mv AT hakwang bis23bispyridin2ylpyrazinek2n2n3palladiumiidinitrateacetonitrilemonosolvate