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(4-Aminopyridine-κN (1))(2,2′-bipyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) unknown solvate
The title compound, [Ru(C(5)H(6)N(2))(C(10)H(8)N(2))(C(15)H(11)N(3))](PF(6))(2) solvent, crystallizes in the triclinic space group P [Image: see text] with one dicationic Ru complex, two PF(6) (−) anions, and undefined solvent in the asymmetric unit. The cation and anions are linked via N—H⋯F hydrog...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462321/ https://www.ncbi.nlm.nih.gov/pubmed/36340290 http://dx.doi.org/10.1107/S241431462100287X |
Sumario: | The title compound, [Ru(C(5)H(6)N(2))(C(10)H(8)N(2))(C(15)H(11)N(3))](PF(6))(2) solvent, crystallizes in the triclinic space group P [Image: see text] with one dicationic Ru complex, two PF(6) (−) anions, and undefined solvent in the asymmetric unit. The cation and anions are linked via N—H⋯F hydrogen bonding. One PF(6) (−) anion is disordered over two positions, with occupancies 0.634 (8) and 0.366 (8). The solvent, which is located in channels in the crystal, is highly disordered. Reflection contributions from the solvent were added to the calculated structure factors using the SQUEEZE routine [Spek (2015) Acta Cryst. C71, 9–18] of the program PLATON, which determined there to be 59 electrons in 264 Å(3) treated this way per unit cell. Because the exact identity and amount of solvent were unknown, no solvent was included in the atom list or molecular formula. [Image: see text] |
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