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(4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate

The title compound, [Ru(C(5)H(6)N(2))(C(10)H(8)N(2))(C(15)H(11)N(3))](PF(6))(2) solvent, crystallizes in the triclinic space group P [Image: see text] with one dicationic Ru complex, two PF(6) (−) anions, and undefined solvent in the asymmetric unit. The cation and anions are linked via N—H⋯F hydrog...

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Autores principales: Reed, Carly R., Garner, Robert N., Brennessel, William W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462321/
https://www.ncbi.nlm.nih.gov/pubmed/36340290
http://dx.doi.org/10.1107/S241431462100287X
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author Reed, Carly R.
Garner, Robert N.
Brennessel, William W.
author_facet Reed, Carly R.
Garner, Robert N.
Brennessel, William W.
author_sort Reed, Carly R.
collection PubMed
description The title compound, [Ru(C(5)H(6)N(2))(C(10)H(8)N(2))(C(15)H(11)N(3))](PF(6))(2) solvent, crystallizes in the triclinic space group P [Image: see text] with one dicationic Ru complex, two PF(6) (−) anions, and undefined solvent in the asymmetric unit. The cation and anions are linked via N—H⋯F hydrogen bonding. One PF(6) (−) anion is disordered over two positions, with occupancies 0.634 (8) and 0.366 (8). The solvent, which is located in channels in the crystal, is highly disordered. Reflection contributions from the solvent were added to the calculated structure factors using the SQUEEZE routine [Spek (2015) Acta Cryst. C71, 9–18] of the program PLATON, which determined there to be 59 electrons in 264 Å(3) treated this way per unit cell. Because the exact identity and amount of solvent were unknown, no solvent was included in the atom list or mol­ecular formula. [Image: see text]
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spelling pubmed-94623212022-11-04 (4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate Reed, Carly R. Garner, Robert N. Brennessel, William W. IUCrdata Data Reports The title compound, [Ru(C(5)H(6)N(2))(C(10)H(8)N(2))(C(15)H(11)N(3))](PF(6))(2) solvent, crystallizes in the triclinic space group P [Image: see text] with one dicationic Ru complex, two PF(6) (−) anions, and undefined solvent in the asymmetric unit. The cation and anions are linked via N—H⋯F hydrogen bonding. One PF(6) (−) anion is disordered over two positions, with occupancies 0.634 (8) and 0.366 (8). The solvent, which is located in channels in the crystal, is highly disordered. Reflection contributions from the solvent were added to the calculated structure factors using the SQUEEZE routine [Spek (2015) Acta Cryst. C71, 9–18] of the program PLATON, which determined there to be 59 electrons in 264 Å(3) treated this way per unit cell. Because the exact identity and amount of solvent were unknown, no solvent was included in the atom list or mol­ecular formula. [Image: see text] International Union of Crystallography 2021-03-23 /pmc/articles/PMC9462321/ /pubmed/36340290 http://dx.doi.org/10.1107/S241431462100287X Text en © Reed et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Reed, Carly R.
Garner, Robert N.
Brennessel, William W.
(4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate
title (4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate
title_full (4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate
title_fullStr (4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate
title_full_unstemmed (4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate
title_short (4-Amino­pyridine-κN (1))(2,2′-bi­pyridine-κ(2) N,N′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) unknown solvate
title_sort (4-amino­pyridine-κn (1))(2,2′-bi­pyridine-κ(2) n,n′)(2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)ruthenium(ii) bis­(hexa­fluorido­phosphate) unknown solvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462321/
https://www.ncbi.nlm.nih.gov/pubmed/36340290
http://dx.doi.org/10.1107/S241431462100287X
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