4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate

The title compound, C(6)H(2)N(3)O(7) (−)·C(10)H(13)Cl(2)N(2) (+), crystallizes with one 1-(2,3-di­chloro-phen­yl)piperazine (DP) cation and one picrate (PA) anion in the asymmetric unit. In the crystal structure, the DP cation and PA anion are inter­connected via several N—H⋯O and C—H⋯O hydrogen bon...

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Autores principales: Sathya, Udhayasuriyan, Nirmal Ram, Jeyaraman Selvaraj, Gomathi, Sundaramoorthy, Ramu, Shyamaladevi, Jegan Jennifer, Samson, Ibrahim, Abdul Razak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462331/
https://www.ncbi.nlm.nih.gov/pubmed/36339106
http://dx.doi.org/10.1107/S2414314621003795
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author Sathya, Udhayasuriyan
Nirmal Ram, Jeyaraman Selvaraj
Gomathi, Sundaramoorthy
Ramu, Shyamaladevi
Jegan Jennifer, Samson
Ibrahim, Abdul Razak
author_facet Sathya, Udhayasuriyan
Nirmal Ram, Jeyaraman Selvaraj
Gomathi, Sundaramoorthy
Ramu, Shyamaladevi
Jegan Jennifer, Samson
Ibrahim, Abdul Razak
author_sort Sathya, Udhayasuriyan
collection PubMed
description The title compound, C(6)H(2)N(3)O(7) (−)·C(10)H(13)Cl(2)N(2) (+), crystallizes with one 1-(2,3-di­chloro-phen­yl)piperazine (DP) cation and one picrate (PA) anion in the asymmetric unit. In the crystal structure, the DP cation and PA anion are inter­connected via several N—H⋯O and C—H⋯O hydrogen bonds. The DP cation and PA anion are further connected through C—Cl⋯π [3.8201 (4), 3.7785 (4) Å] and N—O⋯π [3.7814 (4) Å] inter­actions. The DP cations are further inter­connected via a weak inter­molecular Cl⋯Cl [3.2613 (4) Å] halogen–halogen inter­action. The combination of these supra­molecular inter­actions leads to a herringbone like supra­molecular architecture. [Image: see text]
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spelling pubmed-94623312022-11-04 4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate Sathya, Udhayasuriyan Nirmal Ram, Jeyaraman Selvaraj Gomathi, Sundaramoorthy Ramu, Shyamaladevi Jegan Jennifer, Samson Ibrahim, Abdul Razak IUCrdata Data Reports The title compound, C(6)H(2)N(3)O(7) (−)·C(10)H(13)Cl(2)N(2) (+), crystallizes with one 1-(2,3-di­chloro-phen­yl)piperazine (DP) cation and one picrate (PA) anion in the asymmetric unit. In the crystal structure, the DP cation and PA anion are inter­connected via several N—H⋯O and C—H⋯O hydrogen bonds. The DP cation and PA anion are further connected through C—Cl⋯π [3.8201 (4), 3.7785 (4) Å] and N—O⋯π [3.7814 (4) Å] inter­actions. The DP cations are further inter­connected via a weak inter­molecular Cl⋯Cl [3.2613 (4) Å] halogen–halogen inter­action. The combination of these supra­molecular inter­actions leads to a herringbone like supra­molecular architecture. [Image: see text] International Union of Crystallography 2021-04-13 /pmc/articles/PMC9462331/ /pubmed/36339106 http://dx.doi.org/10.1107/S2414314621003795 Text en © Sathya et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sathya, Udhayasuriyan
Nirmal Ram, Jeyaraman Selvaraj
Gomathi, Sundaramoorthy
Ramu, Shyamaladevi
Jegan Jennifer, Samson
Ibrahim, Abdul Razak
4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate
title 4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate
title_full 4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate
title_fullStr 4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate
title_full_unstemmed 4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate
title_short 4-(2,3-Di­chloro­phen­yl)piperazin-1-ium picrate
title_sort 4-(2,3-di­chloro­phen­yl)piperazin-1-ium picrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462331/
https://www.ncbi.nlm.nih.gov/pubmed/36339106
http://dx.doi.org/10.1107/S2414314621003795
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