Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)

The cationic Zn(II) part of aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate), [Zn(C(8)H(20)N(4))(H(2)O)](ClO(4))(2), exhibits a slightly distorted square-pyramidal coordination environment with a water mol­ecule in the apical position. In the crystal, the macrocyclic ring alternat...

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Detalles Bibliográficos
Autores principales: Ichimaru, Yoshimi, Kato, Koichi, Kurosaki, Hiromasa, Fujioka, Haruto, Sakai, Misa, Yamaguchi, Yoshihiro, Wanchun, Jin, Sugiura, Kirara, Imai, Masanori, Koike, Tohru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462334/
https://www.ncbi.nlm.nih.gov/pubmed/36339098
http://dx.doi.org/10.1107/S2414314621003977
Descripción
Sumario:The cationic Zn(II) part of aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate), [Zn(C(8)H(20)N(4))(H(2)O)](ClO(4))(2), exhibits a slightly distorted square-pyramidal coordination environment with a water mol­ecule in the apical position. In the crystal, the macrocyclic ring alternates between two conformations with equal occupancies. Two of the three perchlorate anions are situated about a twofold rotation axis, and one of them shows disorder of the O atoms with occupancies of 0.62 (7) and 0.38 (7). In the crystal, the complexes are connected by inter­molecular hydrogen bonding via the perchlorate anions. [Image: see text]

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