Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)

The cationic Zn(II) part of aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate), [Zn(C(8)H(20)N(4))(H(2)O)](ClO(4))(2), exhibits a slightly distorted square-pyramidal coordination environment with a water mol­ecule in the apical position. In the crystal, the macrocyclic ring alternat...

Descripción completa

Detalles Bibliográficos
Autores principales: Ichimaru, Yoshimi, Kato, Koichi, Kurosaki, Hiromasa, Fujioka, Haruto, Sakai, Misa, Yamaguchi, Yoshihiro, Wanchun, Jin, Sugiura, Kirara, Imai, Masanori, Koike, Tohru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462334/
https://www.ncbi.nlm.nih.gov/pubmed/36339098
http://dx.doi.org/10.1107/S2414314621003977
_version_ 1784787163163918336
author Ichimaru, Yoshimi
Kato, Koichi
Kurosaki, Hiromasa
Fujioka, Haruto
Sakai, Misa
Yamaguchi, Yoshihiro
Wanchun, Jin
Sugiura, Kirara
Imai, Masanori
Koike, Tohru
author_facet Ichimaru, Yoshimi
Kato, Koichi
Kurosaki, Hiromasa
Fujioka, Haruto
Sakai, Misa
Yamaguchi, Yoshihiro
Wanchun, Jin
Sugiura, Kirara
Imai, Masanori
Koike, Tohru
author_sort Ichimaru, Yoshimi
collection PubMed
description The cationic Zn(II) part of aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate), [Zn(C(8)H(20)N(4))(H(2)O)](ClO(4))(2), exhibits a slightly distorted square-pyramidal coordination environment with a water mol­ecule in the apical position. In the crystal, the macrocyclic ring alternates between two conformations with equal occupancies. Two of the three perchlorate anions are situated about a twofold rotation axis, and one of them shows disorder of the O atoms with occupancies of 0.62 (7) and 0.38 (7). In the crystal, the complexes are connected by inter­molecular hydrogen bonding via the perchlorate anions. [Image: see text]
format Online
Article
Text
id pubmed-9462334
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94623342022-11-04 Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate) Ichimaru, Yoshimi Kato, Koichi Kurosaki, Hiromasa Fujioka, Haruto Sakai, Misa Yamaguchi, Yoshihiro Wanchun, Jin Sugiura, Kirara Imai, Masanori Koike, Tohru IUCrdata Data Reports The cationic Zn(II) part of aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate), [Zn(C(8)H(20)N(4))(H(2)O)](ClO(4))(2), exhibits a slightly distorted square-pyramidal coordination environment with a water mol­ecule in the apical position. In the crystal, the macrocyclic ring alternates between two conformations with equal occupancies. Two of the three perchlorate anions are situated about a twofold rotation axis, and one of them shows disorder of the O atoms with occupancies of 0.62 (7) and 0.38 (7). In the crystal, the complexes are connected by inter­molecular hydrogen bonding via the perchlorate anions. [Image: see text] International Union of Crystallography 2021-04-20 /pmc/articles/PMC9462334/ /pubmed/36339098 http://dx.doi.org/10.1107/S2414314621003977 Text en © Ichimaru et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ichimaru, Yoshimi
Kato, Koichi
Kurosaki, Hiromasa
Fujioka, Haruto
Sakai, Misa
Yamaguchi, Yoshihiro
Wanchun, Jin
Sugiura, Kirara
Imai, Masanori
Koike, Tohru
Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)
title Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)
title_full Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)
title_fullStr Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)
title_full_unstemmed Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)
title_short Aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(II) bis­(perchlorate)
title_sort aqua­(1,4,7,10-tetra­aza­cyclo­dodeca­ne)zinc(ii) bis­(perchlorate)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462334/
https://www.ncbi.nlm.nih.gov/pubmed/36339098
http://dx.doi.org/10.1107/S2414314621003977
work_keys_str_mv AT ichimaruyoshimi aqua14710tetraazacyclododecanezinciibisperchlorate
AT katokoichi aqua14710tetraazacyclododecanezinciibisperchlorate
AT kurosakihiromasa aqua14710tetraazacyclododecanezinciibisperchlorate
AT fujiokaharuto aqua14710tetraazacyclododecanezinciibisperchlorate
AT sakaimisa aqua14710tetraazacyclododecanezinciibisperchlorate
AT yamaguchiyoshihiro aqua14710tetraazacyclododecanezinciibisperchlorate
AT wanchunjin aqua14710tetraazacyclododecanezinciibisperchlorate
AT sugiurakirara aqua14710tetraazacyclododecanezinciibisperchlorate
AT imaimasanori aqua14710tetraazacyclododecanezinciibisperchlorate
AT koiketohru aqua14710tetraazacyclododecanezinciibisperchlorate

Ejemplares similares