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catena-Poly[[bis(1H-indole-5-carboxylato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2) N (1):N (1′)]
The asymmetric unit of the title coordination polymer [Zn(C(9)H(6)NO(2))(2)(C(10)H(8)N(4))]( n ), consists of one Zn(II) cation, one bidentate 1H-indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn(II) ion adopts a distort...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462335/ https://www.ncbi.nlm.nih.gov/pubmed/36338268 http://dx.doi.org/10.1107/S2414314621005228 |
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author | Sathya, Udhayasuriyan Nirmal Ram, Jeyaraman Selvaraj Gomathi, Sundaramoorthy Jegan Jennifer, Samson Abdul Razak, Ibrahim |
author_facet | Sathya, Udhayasuriyan Nirmal Ram, Jeyaraman Selvaraj Gomathi, Sundaramoorthy Jegan Jennifer, Samson Abdul Razak, Ibrahim |
author_sort | Sathya, Udhayasuriyan |
collection | PubMed |
description | The asymmetric unit of the title coordination polymer [Zn(C(9)H(6)NO(2))(2)(C(10)H(8)N(4))]( n ), consists of one Zn(II) cation, one bidentate 1H-indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn(II) ion adopts a distorted octahedral geometry. The coordination polymer is stabilized by a combination of N—H⋯O and C—H⋯π interactions, which leads to the formation of wave-like two-dimensional coordination polymeric layers. [Image: see text] |
format | Online Article Text |
id | pubmed-9462335 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94623352022-11-04 catena-Poly[[bis(1H-indole-5-carboxylato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2) N (1):N (1′)] Sathya, Udhayasuriyan Nirmal Ram, Jeyaraman Selvaraj Gomathi, Sundaramoorthy Jegan Jennifer, Samson Abdul Razak, Ibrahim IUCrdata Data Reports The asymmetric unit of the title coordination polymer [Zn(C(9)H(6)NO(2))(2)(C(10)H(8)N(4))]( n ), consists of one Zn(II) cation, one bidentate 1H-indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn(II) ion adopts a distorted octahedral geometry. The coordination polymer is stabilized by a combination of N—H⋯O and C—H⋯π interactions, which leads to the formation of wave-like two-dimensional coordination polymeric layers. [Image: see text] International Union of Crystallography 2021-05-21 /pmc/articles/PMC9462335/ /pubmed/36338268 http://dx.doi.org/10.1107/S2414314621005228 Text en © Sathya et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Sathya, Udhayasuriyan Nirmal Ram, Jeyaraman Selvaraj Gomathi, Sundaramoorthy Jegan Jennifer, Samson Abdul Razak, Ibrahim catena-Poly[[bis(1H-indole-5-carboxylato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2) N (1):N (1′)] |
title |
catena-Poly[[bis(1H-indole-5-carboxylato-κ(2)
O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2)
N
(1):N
(1′)] |
title_full |
catena-Poly[[bis(1H-indole-5-carboxylato-κ(2)
O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2)
N
(1):N
(1′)] |
title_fullStr |
catena-Poly[[bis(1H-indole-5-carboxylato-κ(2)
O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2)
N
(1):N
(1′)] |
title_full_unstemmed |
catena-Poly[[bis(1H-indole-5-carboxylato-κ(2)
O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2)
N
(1):N
(1′)] |
title_short |
catena-Poly[[bis(1H-indole-5-carboxylato-κ(2)
O,O′)zinc(II)]-μ-4,4′-azobipyridine-κ(2)
N
(1):N
(1′)] |
title_sort | catena-poly[[bis(1h-indole-5-carboxylato-κ(2)
o,o′)zinc(ii)]-μ-4,4′-azobipyridine-κ(2)
n
(1):n
(1′)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462335/ https://www.ncbi.nlm.nih.gov/pubmed/36338268 http://dx.doi.org/10.1107/S2414314621005228 |
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