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catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]

The asymmetric unit of the title coordination polymer [Zn(C(9)H(6)NO(2))(2)(C(10)H(8)N(4))]( n ), consists of one Zn(II) cation, one bidentate 1H-indole-5-carboxyl­ate (I5C) anion and half of a 4,4′-azobi­pyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn(II) ion adopts a distort...

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Autores principales: Sathya, Udhayasuriyan, Nirmal Ram, Jeyaraman Selvaraj, Gomathi, Sundaramoorthy, Jegan Jennifer, Samson, Abdul Razak, Ibrahim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462335/
https://www.ncbi.nlm.nih.gov/pubmed/36338268
http://dx.doi.org/10.1107/S2414314621005228
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author Sathya, Udhayasuriyan
Nirmal Ram, Jeyaraman Selvaraj
Gomathi, Sundaramoorthy
Jegan Jennifer, Samson
Abdul Razak, Ibrahim
author_facet Sathya, Udhayasuriyan
Nirmal Ram, Jeyaraman Selvaraj
Gomathi, Sundaramoorthy
Jegan Jennifer, Samson
Abdul Razak, Ibrahim
author_sort Sathya, Udhayasuriyan
collection PubMed
description The asymmetric unit of the title coordination polymer [Zn(C(9)H(6)NO(2))(2)(C(10)H(8)N(4))]( n ), consists of one Zn(II) cation, one bidentate 1H-indole-5-carboxyl­ate (I5C) anion and half of a 4,4′-azobi­pyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn(II) ion adopts a distorted octa­hedral geometry. The coordination polymer is stabilized by a combination of N—H⋯O and C—H⋯π inter­actions, which leads to the formation of wave-like two-dimensional coordination polymeric layers. [Image: see text]
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spelling pubmed-94623352022-11-04 catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)] Sathya, Udhayasuriyan Nirmal Ram, Jeyaraman Selvaraj Gomathi, Sundaramoorthy Jegan Jennifer, Samson Abdul Razak, Ibrahim IUCrdata Data Reports The asymmetric unit of the title coordination polymer [Zn(C(9)H(6)NO(2))(2)(C(10)H(8)N(4))]( n ), consists of one Zn(II) cation, one bidentate 1H-indole-5-carboxyl­ate (I5C) anion and half of a 4,4′-azobi­pyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn(II) ion adopts a distorted octa­hedral geometry. The coordination polymer is stabilized by a combination of N—H⋯O and C—H⋯π inter­actions, which leads to the formation of wave-like two-dimensional coordination polymeric layers. [Image: see text] International Union of Crystallography 2021-05-21 /pmc/articles/PMC9462335/ /pubmed/36338268 http://dx.doi.org/10.1107/S2414314621005228 Text en © Sathya et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sathya, Udhayasuriyan
Nirmal Ram, Jeyaraman Selvaraj
Gomathi, Sundaramoorthy
Jegan Jennifer, Samson
Abdul Razak, Ibrahim
catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]
title catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]
title_full catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]
title_fullStr catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]
title_full_unstemmed catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]
title_short catena-Poly[[bis­(1H-indole-5-carboxyl­ato-κ(2) O,O′)zinc(II)]-μ-4,4′-azobi­pyridine-κ(2) N (1):N (1′)]
title_sort catena-poly[[bis­(1h-indole-5-carboxyl­ato-κ(2) o,o′)zinc(ii)]-μ-4,4′-azobi­pyridine-κ(2) n (1):n (1′)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462335/
https://www.ncbi.nlm.nih.gov/pubmed/36338268
http://dx.doi.org/10.1107/S2414314621005228
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