(Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate

The title compound, [Co(C(5)H(5))(C(10)H(9)N(2))]PF(6), was synthesized from deproton­ated 1-amino­pyridinium iodide, followed by microwave-assisted nucleophilic aromatic substitution of iodo-cobaltocenium iodide. After anion exchange with potassium hexa­fluorido­phosphate, the title compound crysta...

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Detalles Bibliográficos
Autores principales: Menia, Daniel, Höfer, Thomas, Wurst, Klaus, Bildstein, Benno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462337/
https://www.ncbi.nlm.nih.gov/pubmed/36338271
http://dx.doi.org/10.1107/S2414314621004600
Descripción
Sumario:The title compound, [Co(C(5)H(5))(C(10)H(9)N(2))]PF(6), was synthesized from deproton­ated 1-amino­pyridinium iodide, followed by microwave-assisted nucleophilic aromatic substitution of iodo-cobaltocenium iodide. After anion exchange with potassium hexa­fluorido­phosphate, the title compound crystallizes as orange prisms in the space group Pc. This very stable pyridine nitrene adduct is the first example of a cobaltocenium derivative, formally containing a nitrene nitro­gen species. [Image: see text]

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