(Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate

The title compound, [Co(C(5)H(5))(C(10)H(9)N(2))]PF(6), was synthesized from deproton­ated 1-amino­pyridinium iodide, followed by microwave-assisted nucleophilic aromatic substitution of iodo-cobaltocenium iodide. After anion exchange with potassium hexa­fluorido­phosphate, the title compound crysta...

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Detalles Bibliográficos
Autores principales: Menia, Daniel, Höfer, Thomas, Wurst, Klaus, Bildstein, Benno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462337/
https://www.ncbi.nlm.nih.gov/pubmed/36338271
http://dx.doi.org/10.1107/S2414314621004600
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author Menia, Daniel
Höfer, Thomas
Wurst, Klaus
Bildstein, Benno
author_facet Menia, Daniel
Höfer, Thomas
Wurst, Klaus
Bildstein, Benno
author_sort Menia, Daniel
collection PubMed
description The title compound, [Co(C(5)H(5))(C(10)H(9)N(2))]PF(6), was synthesized from deproton­ated 1-amino­pyridinium iodide, followed by microwave-assisted nucleophilic aromatic substitution of iodo-cobaltocenium iodide. After anion exchange with potassium hexa­fluorido­phosphate, the title compound crystallizes as orange prisms in the space group Pc. This very stable pyridine nitrene adduct is the first example of a cobaltocenium derivative, formally containing a nitrene nitro­gen species. [Image: see text]
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spelling pubmed-94623372022-11-04 (Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate Menia, Daniel Höfer, Thomas Wurst, Klaus Bildstein, Benno IUCrdata Data Reports The title compound, [Co(C(5)H(5))(C(10)H(9)N(2))]PF(6), was synthesized from deproton­ated 1-amino­pyridinium iodide, followed by microwave-assisted nucleophilic aromatic substitution of iodo-cobaltocenium iodide. After anion exchange with potassium hexa­fluorido­phosphate, the title compound crystallizes as orange prisms in the space group Pc. This very stable pyridine nitrene adduct is the first example of a cobaltocenium derivative, formally containing a nitrene nitro­gen species. [Image: see text] International Union of Crystallography 2021-07-05 /pmc/articles/PMC9462337/ /pubmed/36338271 http://dx.doi.org/10.1107/S2414314621004600 Text en © Menia et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Menia, Daniel
Höfer, Thomas
Wurst, Klaus
Bildstein, Benno
(Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
title (Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
title_full (Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
title_fullStr (Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
title_full_unstemmed (Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
title_short (Cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
title_sort (cobaltoceniumyl­amido)­pyridinium hexa­fluorido­phosphate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462337/
https://www.ncbi.nlm.nih.gov/pubmed/36338271
http://dx.doi.org/10.1107/S2414314621004600
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AT hoferthomas cobaltoceniumylamidopyridiniumhexafluoridophosphate
AT wurstklaus cobaltoceniumylamidopyridiniumhexafluoridophosphate
AT bildsteinbenno cobaltoceniumylamidopyridiniumhexafluoridophosphate

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