Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate

The title compound, C(14)H(13)ClN(2)O(2), was obtained during an attempt to grow single crystals of 4-acetyl­phenyl 2-[(3-chloro-2-methyl­phen­yl)amino]­nicotinate in methanol, and was probably generated by alcoholysis. Two intra­molecular hydrogen bonds are formed, one between the N—H group and the...

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Detalles Bibliográficos
Autores principales: Yang, Xing, Long, Sihui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462340/
https://www.ncbi.nlm.nih.gov/pubmed/36338272
http://dx.doi.org/10.1107/S2414314621005393
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author Yang, Xing
Long, Sihui
author_facet Yang, Xing
Long, Sihui
author_sort Yang, Xing
collection PubMed
description The title compound, C(14)H(13)ClN(2)O(2), was obtained during an attempt to grow single crystals of 4-acetyl­phenyl 2-[(3-chloro-2-methyl­phen­yl)amino]­nicotinate in methanol, and was probably generated by alcoholysis. Two intra­molecular hydrogen bonds are formed, one between the N—H group and the carbonyl O atom of the ester and the other between the ortho sp (2)CH group of the benzene ring and the pyridine N atom. Aromatic π–π stacking [shortest centroid–centroid separation = 3.598 (2) Å] is observed in the extended structure. [Image: see text]
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spelling pubmed-94623402022-11-04 Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate Yang, Xing Long, Sihui IUCrdata Data Reports The title compound, C(14)H(13)ClN(2)O(2), was obtained during an attempt to grow single crystals of 4-acetyl­phenyl 2-[(3-chloro-2-methyl­phen­yl)amino]­nicotinate in methanol, and was probably generated by alcoholysis. Two intra­molecular hydrogen bonds are formed, one between the N—H group and the carbonyl O atom of the ester and the other between the ortho sp (2)CH group of the benzene ring and the pyridine N atom. Aromatic π–π stacking [shortest centroid–centroid separation = 3.598 (2) Å] is observed in the extended structure. [Image: see text] International Union of Crystallography 2021-05-25 /pmc/articles/PMC9462340/ /pubmed/36338272 http://dx.doi.org/10.1107/S2414314621005393 Text en © Yang and Long 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Yang, Xing
Long, Sihui
Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
title Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
title_full Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
title_fullStr Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
title_full_unstemmed Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
title_short Methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
title_sort methyl 2-(3-chloro-2-methyl­anilino)pyridine-3-carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462340/
https://www.ncbi.nlm.nih.gov/pubmed/36338272
http://dx.doi.org/10.1107/S2414314621005393
work_keys_str_mv AT yangxing methyl23chloro2methylanilinopyridine3carboxylate
AT longsihui methyl23chloro2methylanilinopyridine3carboxylate

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