8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene

In the tricyclic title compound, C(11)H(12)N(2)OS, the 2,3,4,5-tetra­hydro­pyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclo­hexa-1,3-diene rings while the isoxazole ring is oriented at an acute...

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Autores principales: Abou, Akoun, Bamba, Fanté, Marrot, Jérôme, Yaya, Soro, Coustard, Jean-Marie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462342/
https://www.ncbi.nlm.nih.gov/pubmed/36337322
http://dx.doi.org/10.1107/S241431462100674X
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author Abou, Akoun
Bamba, Fanté
Marrot, Jérôme
Yaya, Soro
Coustard, Jean-Marie
author_facet Abou, Akoun
Bamba, Fanté
Marrot, Jérôme
Yaya, Soro
Coustard, Jean-Marie
author_sort Abou, Akoun
collection PubMed
description In the tricyclic title compound, C(11)H(12)N(2)OS, the 2,3,4,5-tetra­hydro­pyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclo­hexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclo­hexa-1,3-diene ring. In the crystal, mol­ecules associate via C—H⋯N hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional network. [Image: see text]
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spelling pubmed-94623422022-11-04 8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene Abou, Akoun Bamba, Fanté Marrot, Jérôme Yaya, Soro Coustard, Jean-Marie IUCrdata Data Reports In the tricyclic title compound, C(11)H(12)N(2)OS, the 2,3,4,5-tetra­hydro­pyridine ring adopts a half-chair conformation. This ring makes dihedral angles of 27.72 (7) and 45.17 (7)°, respectively, with the isoxazole and the cyclo­hexa-1,3-diene rings while the isoxazole ring is oriented at an acute angle of 63.46 (7)° with respect to the cyclo­hexa-1,3-diene ring. In the crystal, mol­ecules associate via C—H⋯N hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional network. [Image: see text] International Union of Crystallography 2021-06-30 /pmc/articles/PMC9462342/ /pubmed/36337322 http://dx.doi.org/10.1107/S241431462100674X Text en © Abou et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Abou, Akoun
Bamba, Fanté
Marrot, Jérôme
Yaya, Soro
Coustard, Jean-Marie
8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene
title 8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene
title_full 8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene
title_fullStr 8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene
title_full_unstemmed 8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene
title_short 8-Methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5H-1-oxa-2,4-di­aza­ace­naphthyl­ene
title_sort 8-methyl-3-methyl­sulfanyl-8a,8b-di­hydro-5h-1-oxa-2,4-di­aza­ace­naphthyl­ene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462342/
https://www.ncbi.nlm.nih.gov/pubmed/36337322
http://dx.doi.org/10.1107/S241431462100674X
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