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catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]

In the title compound, [CdNi(C(9)H(8)N(2))(2)(CN)(4)]( n ), the Cd and Ni atoms both lie on centres of inversion in space group P2(1)/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the...

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Autores principales: Khelfa, Selma, Touil, Marwa, Setifi, Zouaoui, Setifi, Fatima, Al-Douh, Mohammed Hadi, Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462346/
https://www.ncbi.nlm.nih.gov/pubmed/36337327
http://dx.doi.org/10.1107/S241431462100568X
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author Khelfa, Selma
Touil, Marwa
Setifi, Zouaoui
Setifi, Fatima
Al-Douh, Mohammed Hadi
Glidewell, Christopher
author_facet Khelfa, Selma
Touil, Marwa
Setifi, Zouaoui
Setifi, Fatima
Al-Douh, Mohammed Hadi
Glidewell, Christopher
author_sort Khelfa, Selma
collection PubMed
description In the title compound, [CdNi(C(9)H(8)N(2))(2)(CN)(4)]( n ), the Cd and Ni atoms both lie on centres of inversion in space group P2(1)/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–)( n ) backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H⋯N and C—H⋯N hydrogen bonds, augmented by a π–π stacking inter­action. [Image: see text]
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spelling pubmed-94623462022-11-04 catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N] Khelfa, Selma Touil, Marwa Setifi, Zouaoui Setifi, Fatima Al-Douh, Mohammed Hadi Glidewell, Christopher IUCrdata Data Reports In the title compound, [CdNi(C(9)H(8)N(2))(2)(CN)(4)]( n ), the Cd and Ni atoms both lie on centres of inversion in space group P2(1)/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–)( n ) backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H⋯N and C—H⋯N hydrogen bonds, augmented by a π–π stacking inter­action. [Image: see text] International Union of Crystallography 2021-06-08 /pmc/articles/PMC9462346/ /pubmed/36337327 http://dx.doi.org/10.1107/S241431462100568X Text en © Khelfa et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Khelfa, Selma
Touil, Marwa
Setifi, Zouaoui
Setifi, Fatima
Al-Douh, Mohammed Hadi
Glidewell, Christopher
catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
title catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
title_full catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
title_fullStr catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
title_full_unstemmed catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
title_short catena-Poly[[bis­(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
title_sort catena-poly[[bis­(quinolin-8-amine-κ(2) n,n′)cadmium(ii)]-μ-cyanido-κ(2) n:c-[dicyanidonickel(ii)]-μ-cyanido-κ(2) c:n]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462346/
https://www.ncbi.nlm.nih.gov/pubmed/36337327
http://dx.doi.org/10.1107/S241431462100568X
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