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catena-Poly[[bis(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
In the title compound, [CdNi(C(9)H(8)N(2))(2)(CN)(4)]( n ), the Cd and Ni atoms both lie on centres of inversion in space group P2(1)/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462346/ https://www.ncbi.nlm.nih.gov/pubmed/36337327 http://dx.doi.org/10.1107/S241431462100568X |
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author | Khelfa, Selma Touil, Marwa Setifi, Zouaoui Setifi, Fatima Al-Douh, Mohammed Hadi Glidewell, Christopher |
author_facet | Khelfa, Selma Touil, Marwa Setifi, Zouaoui Setifi, Fatima Al-Douh, Mohammed Hadi Glidewell, Christopher |
author_sort | Khelfa, Selma |
collection | PubMed |
description | In the title compound, [CdNi(C(9)H(8)N(2))(2)(CN)(4)]( n ), the Cd and Ni atoms both lie on centres of inversion in space group P2(1)/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–)( n ) backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H⋯N and C—H⋯N hydrogen bonds, augmented by a π–π stacking interaction. [Image: see text] |
format | Online Article Text |
id | pubmed-9462346 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94623462022-11-04 catena-Poly[[bis(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N] Khelfa, Selma Touil, Marwa Setifi, Zouaoui Setifi, Fatima Al-Douh, Mohammed Hadi Glidewell, Christopher IUCrdata Data Reports In the title compound, [CdNi(C(9)H(8)N(2))(2)(CN)(4)]( n ), the Cd and Ni atoms both lie on centres of inversion in space group P2(1)/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–)( n ) backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H⋯N and C—H⋯N hydrogen bonds, augmented by a π–π stacking interaction. [Image: see text] International Union of Crystallography 2021-06-08 /pmc/articles/PMC9462346/ /pubmed/36337327 http://dx.doi.org/10.1107/S241431462100568X Text en © Khelfa et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Khelfa, Selma Touil, Marwa Setifi, Zouaoui Setifi, Fatima Al-Douh, Mohammed Hadi Glidewell, Christopher catena-Poly[[bis(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N] |
title |
catena-Poly[[bis(quinolin-8-amine-κ(2)
N,N′)cadmium(II)]-μ-cyanido-κ(2)
N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2)
C:N] |
title_full |
catena-Poly[[bis(quinolin-8-amine-κ(2)
N,N′)cadmium(II)]-μ-cyanido-κ(2)
N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2)
C:N] |
title_fullStr |
catena-Poly[[bis(quinolin-8-amine-κ(2)
N,N′)cadmium(II)]-μ-cyanido-κ(2)
N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2)
C:N] |
title_full_unstemmed |
catena-Poly[[bis(quinolin-8-amine-κ(2)
N,N′)cadmium(II)]-μ-cyanido-κ(2)
N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2)
C:N] |
title_short |
catena-Poly[[bis(quinolin-8-amine-κ(2)
N,N′)cadmium(II)]-μ-cyanido-κ(2)
N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2)
C:N] |
title_sort | catena-poly[[bis(quinolin-8-amine-κ(2)
n,n′)cadmium(ii)]-μ-cyanido-κ(2)
n:c-[dicyanidonickel(ii)]-μ-cyanido-κ(2)
c:n] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462346/ https://www.ncbi.nlm.nih.gov/pubmed/36337327 http://dx.doi.org/10.1107/S241431462100568X |
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