Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate

The title compound, C(12)H(17)I(2)O(3)P, was prepared in three steps from p-xylene. Heterodimers between nearly identical mol­ecules are connected via three hydrogen bonds from benzylic and ester methyl­ene groups to phospho­nate. The dimers form chains along the a-axis direction, stabilized by C—H⋯...

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Detalles Bibliográficos
Autores principales: Schollmeyer, Dieter, Sadovski, Oleg, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462347/
https://www.ncbi.nlm.nih.gov/pubmed/36337324
http://dx.doi.org/10.1107/S2414314621006544
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author Schollmeyer, Dieter
Sadovski, Oleg
Detert, Heiner
author_facet Schollmeyer, Dieter
Sadovski, Oleg
Detert, Heiner
author_sort Schollmeyer, Dieter
collection PubMed
description The title compound, C(12)H(17)I(2)O(3)P, was prepared in three steps from p-xylene. Heterodimers between nearly identical mol­ecules are connected via three hydrogen bonds from benzylic and ester methyl­ene groups to phospho­nate. The dimers form chains along the a-axis direction, stabilized by C—H⋯O bridges. [Image: see text]
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spelling pubmed-94623472022-11-04 Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate Schollmeyer, Dieter Sadovski, Oleg Detert, Heiner IUCrdata Data Reports The title compound, C(12)H(17)I(2)O(3)P, was prepared in three steps from p-xylene. Heterodimers between nearly identical mol­ecules are connected via three hydrogen bonds from benzylic and ester methyl­ene groups to phospho­nate. The dimers form chains along the a-axis direction, stabilized by C—H⋯O bridges. [Image: see text] International Union of Crystallography 2021-06-30 /pmc/articles/PMC9462347/ /pubmed/36337324 http://dx.doi.org/10.1107/S2414314621006544 Text en © Schollmeyer et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schollmeyer, Dieter
Sadovski, Oleg
Detert, Heiner
Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
title Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
title_full Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
title_fullStr Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
title_full_unstemmed Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
title_short Diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
title_sort diethyl [(2,5-di­iodo-4-methyl­phen­yl)meth­yl]phospho­nate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462347/
https://www.ncbi.nlm.nih.gov/pubmed/36337324
http://dx.doi.org/10.1107/S2414314621006544
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AT detertheiner diethyl25diiodo4methylphenylmethylphosphonate

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