Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate

The title compound, (NH(4))(4)(C(4)H(12)N(5))(2)[V(10)O(28)]·6H(2)O, crystallizes with the deca­vanadate anion placed on an inversion centre in space group P [Image: see text] . This anion is surrounded by a first shell of ammonium cations and water mol­ecules, forming efficient N—H⋯O and O—H⋯O hydr...

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Autores principales: Polito-Lucas, J. Alberto, Núñez-Ávila, José A., Bernès, Sylvain, Pérez-Benítez, Aarón
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462348/
https://www.ncbi.nlm.nih.gov/pubmed/36337320
http://dx.doi.org/10.1107/S2414314621006349
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author Polito-Lucas, J. Alberto
Núñez-Ávila, José A.
Bernès, Sylvain
Pérez-Benítez, Aarón
author_facet Polito-Lucas, J. Alberto
Núñez-Ávila, José A.
Bernès, Sylvain
Pérez-Benítez, Aarón
author_sort Polito-Lucas, J. Alberto
collection PubMed
description The title compound, (NH(4))(4)(C(4)H(12)N(5))(2)[V(10)O(28)]·6H(2)O, crystallizes with the deca­vanadate anion placed on an inversion centre in space group P [Image: see text] . This anion is surrounded by a first shell of ammonium cations and water mol­ecules, forming efficient N—H⋯O and O—H⋯O hydrogen bonds. A second shell includes metforminium monocations with a twisted geometry, also forming numerous inter­molecular hydrogen bonds. The complex three-dimensional network of non-covalent inter­actions affords a crystal structure in which the cations and anions are densely packed. [Image: see text]
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spelling pubmed-94623482022-11-04 Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate Polito-Lucas, J. Alberto Núñez-Ávila, José A. Bernès, Sylvain Pérez-Benítez, Aarón IUCrdata Data Reports The title compound, (NH(4))(4)(C(4)H(12)N(5))(2)[V(10)O(28)]·6H(2)O, crystallizes with the deca­vanadate anion placed on an inversion centre in space group P [Image: see text] . This anion is surrounded by a first shell of ammonium cations and water mol­ecules, forming efficient N—H⋯O and O—H⋯O hydrogen bonds. A second shell includes metforminium monocations with a twisted geometry, also forming numerous inter­molecular hydrogen bonds. The complex three-dimensional network of non-covalent inter­actions affords a crystal structure in which the cations and anions are densely packed. [Image: see text] International Union of Crystallography 2021-06-25 /pmc/articles/PMC9462348/ /pubmed/36337320 http://dx.doi.org/10.1107/S2414314621006349 Text en © Polito-Lucas et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Polito-Lucas, J. Alberto
Núñez-Ávila, José A.
Bernès, Sylvain
Pérez-Benítez, Aarón
Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate
title Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate
title_full Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate
title_fullStr Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate
title_full_unstemmed Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate
title_short Tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) hexa­hydrate
title_sort tetra­ammonium bis­(metforminium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(v) hexa­hydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462348/
https://www.ncbi.nlm.nih.gov/pubmed/36337320
http://dx.doi.org/10.1107/S2414314621006349
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AT bernessylvain tetraammoniumbismetforminiumdim6oxidotetram3oxidotetradecam2oxidooctaoxidodecavanadiumvhexahydrate
AT perezbenitezaaron tetraammoniumbismetforminiumdim6oxidotetram3oxidotetradecam2oxidooctaoxidodecavanadiumvhexahydrate

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