Barium bis­[tetra­fluorido­bromate(III)]

Single crystals of barium bis­[tetra­fluorido­bromate(III)], Ba[BrF(4)](2), were obtained in the form of tiny blocks. Crystal-structure refinement of Ba[BrF(4)](2) from single-crystal X-ray diffraction data confirmed the previous model obtained on the basis of powder data [Ivlev et al. (2014 ▸). Eur...

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Detalles Bibliográficos
Autores principales: Ivlev, Sergei I., Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462354/
https://www.ncbi.nlm.nih.gov/pubmed/36340658
http://dx.doi.org/10.1107/S2414314621007355
Descripción
Sumario:Single crystals of barium bis­[tetra­fluorido­bromate(III)], Ba[BrF(4)](2), were obtained in the form of tiny blocks. Crystal-structure refinement of Ba[BrF(4)](2) from single-crystal X-ray diffraction data confirmed the previous model obtained on the basis of powder data [Ivlev et al. (2014 ▸). Eur. J. Inorg. Chem. pp. 6261–6267], but with all atoms refined with anisotropic displacement parameters. The crystal structure consists of two symmetry-independent barium cations that are each coordinated by twelve fluorine atoms, forming edge-sharing polyhedra, and an almost square-planar [BrF(4)](−) anion. The compound crystallizes in the Ba[AuF(4)](2) structure type. [Image: see text]

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