Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide

The title compound, [Nb(6)Cl(12)(H(2)O)(6)]I(2), consists of the niobium cluster cation [Nb(6)Cl(12)(H(2)O)(6)](2+) and two non-coordinating, charge-balancing iodide ions. The edges of the Nb(6) octa­hedron are bridged by chlorido ligands. Each Nb atom is further coordinated by a water ligand. The c...

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Detalles Bibliográficos
Autores principales: Schröder, Florian, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462356/
https://www.ncbi.nlm.nih.gov/pubmed/36340657
http://dx.doi.org/10.1107/S2414314621006969
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author Schröder, Florian
Köckerling, Martin
author_facet Schröder, Florian
Köckerling, Martin
author_sort Schröder, Florian
collection PubMed
description The title compound, [Nb(6)Cl(12)(H(2)O)(6)]I(2), consists of the niobium cluster cation [Nb(6)Cl(12)(H(2)O)(6)](2+) and two non-coordinating, charge-balancing iodide ions. The edges of the Nb(6) octa­hedron are bridged by chlorido ligands. Each Nb atom is further coordinated by a water ligand. The cluster cation has a charge of +2, which is balanced by that of two iodide anions. [Image: see text]
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spelling pubmed-94623562022-11-04 Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide Schröder, Florian Köckerling, Martin IUCrdata Data Reports The title compound, [Nb(6)Cl(12)(H(2)O)(6)]I(2), consists of the niobium cluster cation [Nb(6)Cl(12)(H(2)O)(6)](2+) and two non-coordinating, charge-balancing iodide ions. The edges of the Nb(6) octa­hedron are bridged by chlorido ligands. Each Nb atom is further coordinated by a water ligand. The cluster cation has a charge of +2, which is balanced by that of two iodide anions. [Image: see text] International Union of Crystallography 2021-07-20 /pmc/articles/PMC9462356/ /pubmed/36340657 http://dx.doi.org/10.1107/S2414314621006969 Text en © Schröder and Köckerling 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schröder, Florian
Köckerling, Martin
Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
title Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
title_full Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
title_fullStr Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
title_full_unstemmed Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
title_short Hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
title_sort hexa­aquadodeca-μ(2)-chlorido-octa­hedro-hexa­niobium diiodide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462356/
https://www.ncbi.nlm.nih.gov/pubmed/36340657
http://dx.doi.org/10.1107/S2414314621006969
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