Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)

In the title compound, [NiFe(2)(C(5)H(5))(C(9)H(5)F(3)O(2))(2)(C(2)H(6)O)(2)], the central Ni(II) ion is observed in an octa­hedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geom...

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Detalles Bibliográficos
Autores principales: Su, Wenqing, Fu, Tianyue, Xu, Zhongwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462358/
https://www.ncbi.nlm.nih.gov/pubmed/36340661
http://dx.doi.org/10.1107/S2414314621006933
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author Su, Wenqing
Fu, Tianyue
Xu, Zhongwei
author_facet Su, Wenqing
Fu, Tianyue
Xu, Zhongwei
author_sort Su, Wenqing
collection PubMed
description In the title compound, [NiFe(2)(C(5)H(5))(C(9)H(5)F(3)O(2))(2)(C(2)H(6)O)(2)], the central Ni(II) ion is observed in an octa­hedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo­penta­diene rings. Coordinated ethanol mol­ecules are engaged in inter­molecular hydrogen bonds, and the crystal is further stabilized by weak C—H⋯F and C—H⋯π contacts. [Image: see text]
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spelling pubmed-94623582022-11-04 Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II) Su, Wenqing Fu, Tianyue Xu, Zhongwei IUCrdata Data Reports In the title compound, [NiFe(2)(C(5)H(5))(C(9)H(5)F(3)O(2))(2)(C(2)H(6)O)(2)], the central Ni(II) ion is observed in an octa­hedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo­penta­diene rings. Coordinated ethanol mol­ecules are engaged in inter­molecular hydrogen bonds, and the crystal is further stabilized by weak C—H⋯F and C—H⋯π contacts. [Image: see text] International Union of Crystallography 2021-07-13 /pmc/articles/PMC9462358/ /pubmed/36340661 http://dx.doi.org/10.1107/S2414314621006933 Text en © Su et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Su, Wenqing
Fu, Tianyue
Xu, Zhongwei
Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)
title Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)
title_full Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)
title_fullStr Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)
title_full_unstemmed Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)
title_short Bis­(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) O,O′)nickel(II)
title_sort bis­(ethanol-κo)bis(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ(2) o,o′)nickel(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462358/
https://www.ncbi.nlm.nih.gov/pubmed/36340661
http://dx.doi.org/10.1107/S2414314621006933
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