Ethanol(nitrato)[tris­(4-cyano-3-phenyl-1H-pyrazol-1-yl)hydroborato]nickel(II)

The synthesis and structure is reported of Tp(Ph,4CN)Ni(NO(3))(EtOH) or [Ni(C(30)H(19)BN(9))(NO(3))(C(2)H(6)O)], the first half-sandwich complex of a cyano­scorpionate ligand. The pseudo­octa­hedral coordination sphere of the Ni(II) ion is comprised of a tridentate tris­(4-cyano-3-phenyl­pyrazol­yl)...

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Detalles Bibliográficos
Autores principales: Salerno, Elvin V., Kadel, Lava R., Eichhorn, David M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462359/
https://www.ncbi.nlm.nih.gov/pubmed/36340660
http://dx.doi.org/10.1107/S2414314621006908
Descripción
Sumario:The synthesis and structure is reported of Tp(Ph,4CN)Ni(NO(3))(EtOH) or [Ni(C(30)H(19)BN(9))(NO(3))(C(2)H(6)O)], the first half-sandwich complex of a cyano­scorpionate ligand. The pseudo­octa­hedral coordination sphere of the Ni(II) ion is comprised of a tridentate tris­(4-cyano-3-phenyl­pyrazol­yl)borate ligand, a bidentate nitrate ligand and a neutral ethanol ligand. The phenyl substituents on the Tp(Ph,4CN) ligand are relatively parallel to the planes of the ethanol and nitrate ligands. An inter­molecular hydrogen-bonding inter­action is evident between the ethanol OH group and the pyrazole CN substituent. The ethanol ligand was modeled with a 0.572 (13)/0.428 (13) disorder of the methyl C atom. [Image: see text]

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