Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)

In the title complex, [Cu(C(6)H(4)O(2)N)(2)]·2C(9)H(6)O(6)·2H(2)O, the Cu(2+) ion lies on a center of inversion and coordinates with symmetry related pyridine nitro­gen and carboxyl oxygen atoms from two pyridine-2-carb­oxy­lic acid anions, giving rise to a square-planar coordination geometry. There...

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Detalles Bibliográficos
Autores principales: Zhang, Wenkai, Zhang, Bingguang, Sun, Qiaozhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462360/
https://www.ncbi.nlm.nih.gov/pubmed/36340659
http://dx.doi.org/10.1107/S2414314621006726
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author Zhang, Wenkai
Zhang, Bingguang
Sun, Qiaozhen
author_facet Zhang, Wenkai
Zhang, Bingguang
Sun, Qiaozhen
author_sort Zhang, Wenkai
collection PubMed
description In the title complex, [Cu(C(6)H(4)O(2)N)(2)]·2C(9)H(6)O(6)·2H(2)O, the Cu(2+) ion lies on a center of inversion and coordinates with symmetry related pyridine nitro­gen and carboxyl oxygen atoms from two pyridine-2-carb­oxy­lic acid anions, giving rise to a square-planar coordination geometry. There are weak axial bonds between Cu and an O atom of a symmetry-related trimesic acid moieties [Cu⋯O = 2.837 (2) Å] The Cu⋯O weak inter­actions and hydrogen bonds stabilize the whole structure. [Image: see text]
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spelling pubmed-94623602022-11-04 Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2) Zhang, Wenkai Zhang, Bingguang Sun, Qiaozhen IUCrdata Data Reports In the title complex, [Cu(C(6)H(4)O(2)N)(2)]·2C(9)H(6)O(6)·2H(2)O, the Cu(2+) ion lies on a center of inversion and coordinates with symmetry related pyridine nitro­gen and carboxyl oxygen atoms from two pyridine-2-carb­oxy­lic acid anions, giving rise to a square-planar coordination geometry. There are weak axial bonds between Cu and an O atom of a symmetry-related trimesic acid moieties [Cu⋯O = 2.837 (2) Å] The Cu⋯O weak inter­actions and hydrogen bonds stabilize the whole structure. [Image: see text] International Union of Crystallography 2021-07-09 /pmc/articles/PMC9462360/ /pubmed/36340659 http://dx.doi.org/10.1107/S2414314621006726 Text en © Zhang et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zhang, Wenkai
Zhang, Bingguang
Sun, Qiaozhen
Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
title Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
title_full Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
title_fullStr Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
title_full_unstemmed Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
title_short Bis(pyridine-2-carboxyl­ato-κ(2) N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
title_sort bis(pyridine-2-carboxyl­ato-κ(2) n,o)copper(ii)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462360/
https://www.ncbi.nlm.nih.gov/pubmed/36340659
http://dx.doi.org/10.1107/S2414314621006726
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AT sunqiaozhen bispyridine2carboxylatok2nocopperiibenzene135tricarboxylicacidwater122

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