(Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)

A new triazole-based neutral Rh(I) complex, [Rh(Cl(0.846)Br(0.154))(C(6)H(11)N(3))(C(8)H(12))], has been synthesized and structurally characterized. The Rh(I) atom has a distorted square-planar coordination environment, formed by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbe...

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Detalles Bibliográficos
Autores principales: Rushlow, Joshua, Astashkin, Andrei V., Albert, Daniel R., Rajaseelan, Edward
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462365/
https://www.ncbi.nlm.nih.gov/pubmed/36339455
http://dx.doi.org/10.1107/S2414314621008117
Descripción
Sumario:A new triazole-based neutral Rh(I) complex, [Rh(Cl(0.846)Br(0.154))(C(6)H(11)N(3))(C(8)H(12))], has been synthesized and structurally characterized. The Rh(I) atom has a distorted square-planar coordination environment, formed by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter­molecular inter­actions other than van der Waals forces are found in the crystal structure. Diffraction data indicated a two-component inversion twin with a ratio of 0.95 (5):0.05 (5). [Image: see text]

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