(Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)

A new triazole-based neutral Rh(I) complex, [Rh(Cl(0.846)Br(0.154))(C(6)H(11)N(3))(C(8)H(12))], has been synthesized and structurally characterized. The Rh(I) atom has a distorted square-planar coordination environment, formed by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbe...

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Detalles Bibliográficos
Autores principales: Rushlow, Joshua, Astashkin, Andrei V., Albert, Daniel R., Rajaseelan, Edward
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462365/
https://www.ncbi.nlm.nih.gov/pubmed/36339455
http://dx.doi.org/10.1107/S2414314621008117
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author Rushlow, Joshua
Astashkin, Andrei V.
Albert, Daniel R.
Rajaseelan, Edward
author_facet Rushlow, Joshua
Astashkin, Andrei V.
Albert, Daniel R.
Rajaseelan, Edward
author_sort Rushlow, Joshua
collection PubMed
description A new triazole-based neutral Rh(I) complex, [Rh(Cl(0.846)Br(0.154))(C(6)H(11)N(3))(C(8)H(12))], has been synthesized and structurally characterized. The Rh(I) atom has a distorted square-planar coordination environment, formed by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter­molecular inter­actions other than van der Waals forces are found in the crystal structure. Diffraction data indicated a two-component inversion twin with a ratio of 0.95 (5):0.05 (5). [Image: see text]
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spelling pubmed-94623652022-11-04 (Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I) Rushlow, Joshua Astashkin, Andrei V. Albert, Daniel R. Rajaseelan, Edward IUCrdata Data Reports A new triazole-based neutral Rh(I) complex, [Rh(Cl(0.846)Br(0.154))(C(6)H(11)N(3))(C(8)H(12))], has been synthesized and structurally characterized. The Rh(I) atom has a distorted square-planar coordination environment, formed by a bidentate cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter­molecular inter­actions other than van der Waals forces are found in the crystal structure. Diffraction data indicated a two-component inversion twin with a ratio of 0.95 (5):0.05 (5). [Image: see text] International Union of Crystallography 2021-08-13 /pmc/articles/PMC9462365/ /pubmed/36339455 http://dx.doi.org/10.1107/S2414314621008117 Text en © Rushlow et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Rushlow, Joshua
Astashkin, Andrei V.
Albert, Daniel R.
Rajaseelan, Edward
(Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)
title (Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)
title_full (Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)
title_fullStr (Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)
title_full_unstemmed (Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)
title_short (Chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(I)
title_sort (chlorido/bromido)[(1,2,5,6-η)-cyclo­octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl­idene)rhodium(i)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462365/
https://www.ncbi.nlm.nih.gov/pubmed/36339455
http://dx.doi.org/10.1107/S2414314621008117
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