Cargando…

Ultrafast Charge Relocation Dynamics in Enol–Keto Tautomerization Monitored with a Local Soft-X-ray Probe

[Image: see text] Proton-coupled electron transfer (PCET) is the underlying mechanism governing important reactions ranging from water splitting in photosynthesis to oxygen reduction in hydrogen fuel cells. The interplay of proton and electronic charge distribution motions can vary from sequential t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Soley, Micheline B., Videla, Pablo E., Nibbering, Erik T. J., Batista, Victor S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9465716/ https://www.ncbi.nlm.nih.gov/pubmed/36018775 http://dx.doi.org/10.1021/acs.jpclett.2c02037

Ejemplares similares

Keto-Enol Tautomerism in Passerini and Ugi Adducts
por: Pertejo, Pablo, et al.
Publicado: (2021)

Vibronic Dynamics of Photodissociating ICN from Simulations of Ultrafast X‐Ray Absorption Spectroscopy
por: Morzan, Uriel N., et al.
Publicado: (2020)

Theoretical Study on the Epimerization of Azlactone Rings: Keto–Enol Tautomerism or Base-Mediated Racemization?
por: de Castro, Pedro P., et al.
Publicado: (2018)

Lignin Intermediates on Palladium: Insights into Keto‐Enol Tautomerization from Theoretical Modelling
por: de Andrade, Ageo Meier, et al.
Publicado: (2020)

High-yield and sustainable synthesis of quinoidal compounds assisted by keto–enol tautomerism
por: Wang, Cheng, et al.
Publicado: (2021)

First-Principles Study of the Dispersion Effects in the Structures and Keto–Enol Tautomerization of Curcumin
por: Madinah, Roichatul, et al.
Publicado: (2023)

New Precursors to 3-Sulfanylhexan-1-ol? Investigating the Keto–Enol Tautomerism of 3-S-Glutathionylhexanal
por: Muhl, Jennifer R., et al.
Publicado: (2021)

DFT Study To Explore the Importance of Ring Size and Effect of Solvents on the Keto–Enol Tautomerization Process of α- and β-Cyclodiones
por: Jana, Kalyanashis, et al.
Publicado: (2018)

Dual-Mode Multiple Ion Sensing via Analyte-Specific Modulation of Keto–Enol Tautomerization of an ESIPT Active Pyrene Derivative: Experimental Findings and Computational Rationalization
por: Paul, Suvendu, et al.
Publicado: (2023)

Synthesis, Spectroscopic Studies and Keto-Enol Tautomerism of Novel 1,3,4-Thiadiazole Derivative Containing 3-Mercaptobutan-2-one and Quinazolin-4-one Moieties
por: Mohammed, Sewara J., et al.
Publicado: (2020)

Use of activated enol ethers in the synthesis of pyrazoles: reactions with hydrazine and a study of pyrazole tautomerism
por: Tarabová, Denisa, et al.
Publicado: (2014)

Investigating the Spectroscopy of the Gas Phase Guanine–Cytosine Pair: Keto versus Enol Configurations
por: Botti, Giacomo, et al.
Publicado: (2023)

Medicinal Plant Using Ground State Stabilization of Natural Antioxidant Curcumin by Keto-Enol Tautomerisation
por: Manimaran, S., et al.
Publicado: (2018)

Unravelling the Keto–Enol Tautomer Dependent Photochemistry and Degradation Pathways of the Protonated UVA Filter Avobenzone
por: Berenbeim, Jacob A., et al.
Publicado: (2020)

Construction of highly-stable covalent organic framework with combined enol-imine and keto-enamine linkages
por: Jiang, Jian, et al.
Publicado: (2023)

Breslow Intermediates (Amino Enols) and Their Keto Tautomers: First Gas‐Phase Characterization by IR Ion Spectroscopy
por: Paul, Mathias, et al.
Publicado: (2020)

Enol-mediated delivery of H(2)Se from γ-keto selenides: mechanistic insight and evaluation
por: Hankins, Rynne A., et al.
Publicado: (2022)

Voltage-driven control of single-molecule keto-enol equilibrium in a two-terminal junction system
por: Tang, Chun, et al.
Publicado: (2023)

Ir-Catalyzed Chemo-, Regio-, and Enantioselective Allylic Enolization of 6,6-Dimethyl-3-((trimethylsilyl)oxy)cyclohex-2-en-1-one Involving Keto-Enol Isomerization
por: Wang, Xiao-Lin, et al.
Publicado: (2022)

Synthesis, Biochemical Characterization, and Theoretical Studies of Novel β-Keto-enol Pyridine and Furan Derivatives as Potent Antifungal Agents
por: Tighadouini, Said, et al.
Publicado: (2020)

Underdamped longitudinal soft modes in ionic crystallites—lattice and charge motions observed by ultrafast x-ray diffraction
por: Gonzalez-Vallejo, Isabel, et al.
Publicado: (2022)

A liquid flatjet system for solution phase soft-x-ray spectroscopy
por: Ekimova, Maria, et al.
Publicado: (2015)

Ultrafast X-ray diffraction probe of terahertz field-driven soft mode dynamics in SrTiO(3)
por: Kozina, M., et al.
Publicado: (2017)

X-ray optics for advanced ultrafast pump–probe X-ray experiments at SACLA
por: Katayama, Tetsuo, et al.
Publicado: (2019)

Synthesis of Novel β-Keto-Enol Derivatives Tethered Pyrazole, Pyridine and Furan as New Potential Antifungal and Anti-Breast Cancer Agents
por: Radi, Smaail, et al.
Publicado: (2015)

Versatile soft X-ray-optical cross-correlator for ultrafast applications
por: Schick, Daniel, et al.
Publicado: (2016)

Basic studies toward ultrafast soft x-ray photoelectron diffraction; its application to probing local structure in iodobenzene molecules
por: Teramoto, T., et al.
Publicado: (2022)

Photoinduced molecular chirality probed by ultrafast resonant X-ray spectroscopy
por: Rouxel, Jérémy R., et al.
Publicado: (2017)

Tautomeric Forms of Metarhodopsin
por: Matthews, Rowena G., et al.
Publicado: (1963)

Tautomerism in large databases
por: Sitzmann, Markus, et al.
Publicado: (2010)

Tautomerism of Guanine Analogues
por: Štoček, Jakub Radek, et al.
Publicado: (2020)

Ultrafast Proton Transfer Pathways Mediated by Amphoteric Imidazole
por: Codescu, Marius-Andrei, et al.
Publicado: (2023)

Soft-mode driven polarity reversal in ferroelectrics mapped by ultrafast x-ray diffraction
por: Hauf, Christoph, et al.
Publicado: (2018)

β-Keto-enol Tethered Pyridine and Thiophene: Synthesis, Crystal Structure Determination and Its Organic Immobilization on Silica for Efficient Solid-Liquid Extraction of Heavy Metals
por: Radi, Smaail, et al.
Publicado: (2016)

Role of tautomerism in RNA biochemistry
por: Singh, Vipender, et al.
Publicado: (2015)

The Allylic Alkylation of Ketone Enolates
por: Junk, Lukas, et al.
Publicado: (2020)

Ultrafast Charge Transfer in Nickel Phthalocyanine Probed by Femtosecond Raman-Induced Kerr Effect Spectroscopy
por: Balakrishnan, Gurusamy, et al.
Publicado: (2014)

Phonon driven charge dynamics in polycrystalline acetylsalicylic acid mapped by ultrafast x-ray diffraction
por: Hauf, Christoph, et al.
Publicado: (2019)

Stable acyclic aliphatic solid enols: synthesis, characterization, X-ray structure analysis and calculations
por: Zhou, Yu-Qiang, et al.
Publicado: (2013)

Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates
por: Chen, Wenyong, et al.
Publicado: (2014)

Cannot write session to /tmp/vufind_sessions/sess_magsv52caujq1b8ihh444imd11