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Anion-assisted amidinium exchange and metathesis

Dynamic covalent chemistry has become an invaluable tool for the design and preparation of adaptable yet robust molecular systems. Herein we explore the scope of a largely overlooked dynamic covalent reaction – amidinium exchange – and report on conditions that allow formal amidinium metathesis reac...

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Detalles Bibliográficos
Autores principales: Borodin, Oleg, Shchukin, Yevhenii, Schmid, Jonas, von Delius, Max
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9469691/
https://www.ncbi.nlm.nih.gov/pubmed/35997205
http://dx.doi.org/10.1039/d2cc03425e
Descripción
Sumario:Dynamic covalent chemistry has become an invaluable tool for the design and preparation of adaptable yet robust molecular systems. Herein we explore the scope of a largely overlooked dynamic covalent reaction – amidinium exchange – and report on conditions that allow formal amidinium metathesis reactions.