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Determination of the iron(IV) local spin states of the Q intermediate of soluble methane monooxygenase by Kβ X-ray emission spectroscopy

Soluble methane monooxygenase (sMMO) facilitates the conversion of methane to methanol at a non-heme Fe(IV)(2) intermediate MMOH(Q), which is formed in the active site of the sMMO hydroxylase component (MMOH) during the catalytic cycle. Other biological systems also employ high-valent Fe(IV) sites i...

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Detalles Bibliográficos
Autores principales:	Cutsail, George E., Banerjee, Rahul, Rice, Derek B., McCubbin Stepanic, Olivia, Lipscomb, John D., DeBeer, Serena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Springer International Publishing 2022
Materias:	Original Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9470658/ https://www.ncbi.nlm.nih.gov/pubmed/35988092 http://dx.doi.org/10.1007/s00775-022-01953-4

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