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Metal–organic frameworks as O(2)-selective adsorbents for air separations
Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne scale, primarily through energy-intensive cryogenic distillation of air. The realization of large-scale adsorption-based air separations could enable a significant reduction in associated worldwide energy consump...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473493/ https://www.ncbi.nlm.nih.gov/pubmed/36277628 http://dx.doi.org/10.1039/d2sc03577d |
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author | Jaramillo, David E. Jaffe, Adam Snyder, Benjamin E. R. Smith, Alex Taw, Eric Rohde, Rachel C. Dods, Matthew N. DeSnoo, William Meihaus, Katie R. Harris, T. David Neaton, Jeffrey B. Long, Jeffrey R. |
author_facet | Jaramillo, David E. Jaffe, Adam Snyder, Benjamin E. R. Smith, Alex Taw, Eric Rohde, Rachel C. Dods, Matthew N. DeSnoo, William Meihaus, Katie R. Harris, T. David Neaton, Jeffrey B. Long, Jeffrey R. |
author_sort | Jaramillo, David E. |
collection | PubMed |
description | Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne scale, primarily through energy-intensive cryogenic distillation of air. The realization of large-scale adsorption-based air separations could enable a significant reduction in associated worldwide energy consumption and would constitute an important component of broader efforts to combat climate change. Certain small-scale air separations are carried out using N(2)-selective adsorbents, although the low capacities, poor selectivities, and high regeneration energies associated with these materials limit the extent of their usage. In contrast, the realization of O(2)-selective adsorbents may facilitate more widespread adoption of adsorptive air separations, which could enable the decentralization of O(2) production and utilization and advance new uses for O(2). Here, we present a detailed evaluation of the potential of metal–organic frameworks (MOFs) to serve as O(2)-selective adsorbents for air separations. Drawing insights from biological and molecular systems that selectively bind O(2), we survey the field of O(2)-selective MOFs, highlighting progress and identifying promising areas for future exploration. As a guide for further research, the importance of moving beyond the traditional evaluation of O(2) adsorption enthalpy, ΔH, is emphasized, and the free energy of O(2) adsorption, ΔG, is discussed as the key metric for understanding and predicting MOF performance under practical conditions. Based on a proof-of-concept assessment of O(2) binding carried out for eight different MOFs using experimentally derived capacities and thermodynamic parameters, we identify two existing materials and one proposed framework with nearly optimal ΔG values for operation under user-defined conditions. While enhancements are still needed in other material properties, the insights from the assessments herein serve as a guide for future materials design and evaluation. Computational approaches based on density functional theory with periodic boundary conditions are also discussed as complementary to experimental efforts, and new predictions enable identification of additional promising MOF systems for investigation. |
format | Online Article Text |
id | pubmed-9473493 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-94734932022-10-20 Metal–organic frameworks as O(2)-selective adsorbents for air separations Jaramillo, David E. Jaffe, Adam Snyder, Benjamin E. R. Smith, Alex Taw, Eric Rohde, Rachel C. Dods, Matthew N. DeSnoo, William Meihaus, Katie R. Harris, T. David Neaton, Jeffrey B. Long, Jeffrey R. Chem Sci Chemistry Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne scale, primarily through energy-intensive cryogenic distillation of air. The realization of large-scale adsorption-based air separations could enable a significant reduction in associated worldwide energy consumption and would constitute an important component of broader efforts to combat climate change. Certain small-scale air separations are carried out using N(2)-selective adsorbents, although the low capacities, poor selectivities, and high regeneration energies associated with these materials limit the extent of their usage. In contrast, the realization of O(2)-selective adsorbents may facilitate more widespread adoption of adsorptive air separations, which could enable the decentralization of O(2) production and utilization and advance new uses for O(2). Here, we present a detailed evaluation of the potential of metal–organic frameworks (MOFs) to serve as O(2)-selective adsorbents for air separations. Drawing insights from biological and molecular systems that selectively bind O(2), we survey the field of O(2)-selective MOFs, highlighting progress and identifying promising areas for future exploration. As a guide for further research, the importance of moving beyond the traditional evaluation of O(2) adsorption enthalpy, ΔH, is emphasized, and the free energy of O(2) adsorption, ΔG, is discussed as the key metric for understanding and predicting MOF performance under practical conditions. Based on a proof-of-concept assessment of O(2) binding carried out for eight different MOFs using experimentally derived capacities and thermodynamic parameters, we identify two existing materials and one proposed framework with nearly optimal ΔG values for operation under user-defined conditions. While enhancements are still needed in other material properties, the insights from the assessments herein serve as a guide for future materials design and evaluation. Computational approaches based on density functional theory with periodic boundary conditions are also discussed as complementary to experimental efforts, and new predictions enable identification of additional promising MOF systems for investigation. The Royal Society of Chemistry 2022-08-11 /pmc/articles/PMC9473493/ /pubmed/36277628 http://dx.doi.org/10.1039/d2sc03577d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Jaramillo, David E. Jaffe, Adam Snyder, Benjamin E. R. Smith, Alex Taw, Eric Rohde, Rachel C. Dods, Matthew N. DeSnoo, William Meihaus, Katie R. Harris, T. David Neaton, Jeffrey B. Long, Jeffrey R. Metal–organic frameworks as O(2)-selective adsorbents for air separations |
title | Metal–organic frameworks as O(2)-selective adsorbents for air separations |
title_full | Metal–organic frameworks as O(2)-selective adsorbents for air separations |
title_fullStr | Metal–organic frameworks as O(2)-selective adsorbents for air separations |
title_full_unstemmed | Metal–organic frameworks as O(2)-selective adsorbents for air separations |
title_short | Metal–organic frameworks as O(2)-selective adsorbents for air separations |
title_sort | metal–organic frameworks as o(2)-selective adsorbents for air separations |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473493/ https://www.ncbi.nlm.nih.gov/pubmed/36277628 http://dx.doi.org/10.1039/d2sc03577d |
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