Cyclooctatetraenide-based single-ion magnets featuring bulky cyclopentadienyl ligand

We report a family of organometallic rare-earth complexes with the general formula (COT)M(Cp(ttt)) (where (COT)(2−) = cyclooctatetraenide, (Cp(ttt))(−) = 1,2,4-tri(tert-butyl)cyclopentadienide, M = Y(iii), Nd(iii), Dy(iii) and Er(iii)). Similarly to the prototypical Er(iii) analog featuring pentamet...

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Detalles Bibliográficos
Autores principales: Korzyński, Maciej Damian, Bernhardt, Moritz, Romankov, Vladyslav, Dreiser, Jan, Matmon, Guy, Pointillart, Fabrice, Le Guennic, Boris, Cador, Olivier, Copéret, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9473503/
https://www.ncbi.nlm.nih.gov/pubmed/36277624
http://dx.doi.org/10.1039/d2sc02560d

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