Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters

Herein, we report a Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence between diarylphosphonates or -phosphinates and α-pyridinealdehydes to access valuable phosphoric ester compounds. This transformation provides an extended substrate scope that is complementary to similar...

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Detalles Bibliográficos
Autores principales: Yang, Jin, Qian, Dang-Wei, Yang, Shang-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9475178/
https://www.ncbi.nlm.nih.gov/pubmed/36128430
http://dx.doi.org/10.3762/bjoc.18.123
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author Yang, Jin
Qian, Dang-Wei
Yang, Shang-Dong
author_facet Yang, Jin
Qian, Dang-Wei
Yang, Shang-Dong
author_sort Yang, Jin
collection PubMed
description Herein, we report a Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence between diarylphosphonates or -phosphinates and α-pyridinealdehydes to access valuable phosphoric ester compounds. This transformation provides an extended substrate scope that is complementary to similar previously reported base-catalyzed transformations.
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spelling pubmed-94751782022-09-19 Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters Yang, Jin Qian, Dang-Wei Yang, Shang-Dong Beilstein J Org Chem Letter Herein, we report a Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence between diarylphosphonates or -phosphinates and α-pyridinealdehydes to access valuable phosphoric ester compounds. This transformation provides an extended substrate scope that is complementary to similar previously reported base-catalyzed transformations. Beilstein-Institut 2022-09-09 /pmc/articles/PMC9475178/ /pubmed/36128430 http://dx.doi.org/10.3762/bjoc.18.123 Text en Copyright © 2022, Yang et al. https://creativecommons.org/licenses/by/4.0/This is an open access article licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-journals.org/bjoc/terms/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this article could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material.
spellingShingle Letter
Yang, Jin
Qian, Dang-Wei
Yang, Shang-Dong
Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
title Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
title_full Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
title_fullStr Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
title_full_unstemmed Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
title_short Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
title_sort lewis acid-catalyzed pudovik reaction–phospha-brook rearrangement sequence to access phosphoric esters
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9475178/
https://www.ncbi.nlm.nih.gov/pubmed/36128430
http://dx.doi.org/10.3762/bjoc.18.123
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AT yangshangdong lewisacidcatalyzedpudovikreactionphosphabrookrearrangementsequencetoaccessphosphoricesters

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