Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes

A straightforward electro-conversion of cumene into acetophenone has been reported using boron-doped diamond (BDD) electrodes. This particular conversion is driven by the addition reaction of a cathodically generated hydroperoxide anion to an anodically generated cumyl cation, where the BDD’s wide p...

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Autores principales: Kitano, Mana, Saitoh, Tsuyoshi, Nishiyama, Shigeru, Einaga, Yasuaki, Yamamoto, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9475189/
https://www.ncbi.nlm.nih.gov/pubmed/36128427
http://dx.doi.org/10.3762/bjoc.18.119
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author Kitano, Mana
Saitoh, Tsuyoshi
Nishiyama, Shigeru
Einaga, Yasuaki
Yamamoto, Takashi
author_facet Kitano, Mana
Saitoh, Tsuyoshi
Nishiyama, Shigeru
Einaga, Yasuaki
Yamamoto, Takashi
author_sort Kitano, Mana
collection PubMed
description A straightforward electro-conversion of cumene into acetophenone has been reported using boron-doped diamond (BDD) electrodes. This particular conversion is driven by the addition reaction of a cathodically generated hydroperoxide anion to an anodically generated cumyl cation, where the BDD’s wide potential window enables the direct anodic oxidation of cumene into the cumyl cation. Since electricity is directly employed as the oxidizing and reducing reagents, the present protocol is easy to use, suitable for scale-up, and inherently safe.
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spelling pubmed-94751892022-09-19 Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes Kitano, Mana Saitoh, Tsuyoshi Nishiyama, Shigeru Einaga, Yasuaki Yamamoto, Takashi Beilstein J Org Chem Letter A straightforward electro-conversion of cumene into acetophenone has been reported using boron-doped diamond (BDD) electrodes. This particular conversion is driven by the addition reaction of a cathodically generated hydroperoxide anion to an anodically generated cumyl cation, where the BDD’s wide potential window enables the direct anodic oxidation of cumene into the cumyl cation. Since electricity is directly employed as the oxidizing and reducing reagents, the present protocol is easy to use, suitable for scale-up, and inherently safe. Beilstein-Institut 2022-09-07 /pmc/articles/PMC9475189/ /pubmed/36128427 http://dx.doi.org/10.3762/bjoc.18.119 Text en Copyright © 2022, Kitano et al. https://creativecommons.org/licenses/by/4.0/This is an open access article licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-journals.org/bjoc/terms/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this article could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material.
spellingShingle Letter
Kitano, Mana
Saitoh, Tsuyoshi
Nishiyama, Shigeru
Einaga, Yasuaki
Yamamoto, Takashi
Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
title Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
title_full Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
title_fullStr Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
title_full_unstemmed Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
title_short Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
title_sort electro-conversion of cumene into acetophenone using boron-doped diamond electrodes
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9475189/
https://www.ncbi.nlm.nih.gov/pubmed/36128427
http://dx.doi.org/10.3762/bjoc.18.119
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