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Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic Surfactant with High Interfacial Activity
[Image: see text] The wide application of surfactants has a harmful effect on the environment, drawing more attention to the development and application of low-toxicity surfactants. A salt-tolerant and low-toxicity biobased zwitterionic surfactant, N,N-dimethyl-N-[2-hydroxy-3-sulfo-propyl]-N-benzylo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9476214/ https://www.ncbi.nlm.nih.gov/pubmed/36120073 http://dx.doi.org/10.1021/acsomega.2c04642 |
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author | Lang, Jian-Qiao Mtui, Homely Isaya Gang, Hong-ze Mu, Bo-Zhong Yang, Shi-Zhong |
author_facet | Lang, Jian-Qiao Mtui, Homely Isaya Gang, Hong-ze Mu, Bo-Zhong Yang, Shi-Zhong |
author_sort | Lang, Jian-Qiao |
collection | PubMed |
description | [Image: see text] The wide application of surfactants has a harmful effect on the environment, drawing more attention to the development and application of low-toxicity surfactants. A salt-tolerant and low-toxicity biobased zwitterionic surfactant, N,N-dimethyl-N-[2-hydroxy-3-sulfo-propyl]-N-benzyloxyoctadecanoyl-1,3-propanediamine (SPBOPA), was prepared from the oleic acid extracted from waste oils and anise ether extracted from the tarragon. The final surfactant structure was confirmed using gas chromatography–mass spectrometry (GC–MS), liquid chromatography–mass spectrometry (LC–MS), and (1)H nuclear magnetic resonance (NMR) spectroscopy. The SPBOPA surfactant could reduce the interfacial tension between crude oil and formation brine to ultralow (5.2 × 10(–4) mN/m) at a low dosage without extra alkali. It still had good interfacial properties in NaCl up to 60 g/L, Ca(2+) up to 2000 mg/L, and temperature up to 100 °C. Furthermore, SPBOPA had strong antidilution and antiadsorption properties with low toxicity as demonstrated by the high LD(50) value of >5000 mg/kg·BW. It could also enhance the wetting ability of crude oil surfaces. Meanwhile, it showed a high biodegradability in the environment. All of the results achieved in this work confirmed that the SPBOPA surfactant is a more robust and promising biobased surfactant candidate than traditional surfactants as an eco-friendly surfactant for enhanced oil recovery (EOR). |
format | Online Article Text |
id | pubmed-9476214 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-94762142022-09-16 Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic Surfactant with High Interfacial Activity Lang, Jian-Qiao Mtui, Homely Isaya Gang, Hong-ze Mu, Bo-Zhong Yang, Shi-Zhong ACS Omega [Image: see text] The wide application of surfactants has a harmful effect on the environment, drawing more attention to the development and application of low-toxicity surfactants. A salt-tolerant and low-toxicity biobased zwitterionic surfactant, N,N-dimethyl-N-[2-hydroxy-3-sulfo-propyl]-N-benzyloxyoctadecanoyl-1,3-propanediamine (SPBOPA), was prepared from the oleic acid extracted from waste oils and anise ether extracted from the tarragon. The final surfactant structure was confirmed using gas chromatography–mass spectrometry (GC–MS), liquid chromatography–mass spectrometry (LC–MS), and (1)H nuclear magnetic resonance (NMR) spectroscopy. The SPBOPA surfactant could reduce the interfacial tension between crude oil and formation brine to ultralow (5.2 × 10(–4) mN/m) at a low dosage without extra alkali. It still had good interfacial properties in NaCl up to 60 g/L, Ca(2+) up to 2000 mg/L, and temperature up to 100 °C. Furthermore, SPBOPA had strong antidilution and antiadsorption properties with low toxicity as demonstrated by the high LD(50) value of >5000 mg/kg·BW. It could also enhance the wetting ability of crude oil surfaces. Meanwhile, it showed a high biodegradability in the environment. All of the results achieved in this work confirmed that the SPBOPA surfactant is a more robust and promising biobased surfactant candidate than traditional surfactants as an eco-friendly surfactant for enhanced oil recovery (EOR). American Chemical Society 2022-09-01 /pmc/articles/PMC9476214/ /pubmed/36120073 http://dx.doi.org/10.1021/acsomega.2c04642 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Lang, Jian-Qiao Mtui, Homely Isaya Gang, Hong-ze Mu, Bo-Zhong Yang, Shi-Zhong Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic Surfactant with High Interfacial Activity |
title | Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic
Surfactant with High Interfacial Activity |
title_full | Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic
Surfactant with High Interfacial Activity |
title_fullStr | Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic
Surfactant with High Interfacial Activity |
title_full_unstemmed | Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic
Surfactant with High Interfacial Activity |
title_short | Highly Ca(2+)-Ion-Tolerant Biobased Zwitterionic
Surfactant with High Interfacial Activity |
title_sort | highly ca(2+)-ion-tolerant biobased zwitterionic
surfactant with high interfacial activity |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9476214/ https://www.ncbi.nlm.nih.gov/pubmed/36120073 http://dx.doi.org/10.1021/acsomega.2c04642 |
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