Flexible and Conductive Polymer Threads for Efficient Fiber-Shaped Supercapacitors via Vapor Copolymerization

[Image: see text] Flexible fiber electrodes are critical for high-performance fiber and wearable electronics. In this work, we presented a highly conductive all-polymer fiber electrode by vapor copolymerization of 2,5-dibromo-3,4-vinyldioxythiophene (DBEDOT) and 2,5-diiodo-3,4-vinyldioxythiophene (DIEDOT) monomers on commonly used polyester threads (PETs) at a temperature as low as 80 °C. The poly(3,4-ethylenedioxythiophene) (PEDOT)-coated PET threads maintain excellent flexibility and show conductivity of 7.93 S cm(–1), nearly four times higher than that reported previously via homopolymerization of DBEDOT monomer. A MnO(2) active layer was embedded into the PEDOT double layers, and the flexible fiber composite electrode showed a high linear specific capacitance of 157 mF cm(–1) and improved stability, retaining 86.5% capacitance after 5000 cycles. Fiber-shaped solid-state supercapacitors (FSSCs) based on the composite electrodes were assembled, and they displayed superior electrochemical performance. This work provides a new approach to realize high-performance and stable wearable electronics.