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Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61–99% yields in the presence of a PN(H)P-based ruthenium catalyst...

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Detalles Bibliográficos
Autores principales: Romero, R. Martin, Thyagarajan, Neethu, Hellou, Nora, Chauvier, Clément, Godou, Timothé, Anthore-Dalion, Lucile, Cantat, Thibault
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9476892/
https://www.ncbi.nlm.nih.gov/pubmed/35522145
http://dx.doi.org/10.1039/d2cc00666a

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