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Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane

The dehydropolymerisation of phenylsilane is investigated using group 4 metallocene amide complexes as catalysts. The dinuclear zirconocene amide complex Cp(2)Zr(NMe(2))(μ-Me(3)SiC(3)SiMe(3))Zr(NMe(2))Cp(2) (2) (Cp = η(5)-cyclopentadienyl) shows high activity in dehydrocoupling reactions, producing...

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Detalles Bibliográficos
Autores principales:	Lindenau, Kevin, Spannenberg, Anke, Reiß, Fabian, Beweries, Torsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9477068/ https://www.ncbi.nlm.nih.gov/pubmed/36275119 http://dx.doi.org/10.1039/d2ra04955d

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