Role of the Triplet State and Protein Dynamics in the Formation and Stability of the Tryptophan Radical in an Apoazurin Mutant

[Image: see text] The protein, azurin, has enabled the study of the tryptophan radical. Upon UV excitation of tyrosine-deficient apoazurin and in the presence of a Co(III) electron acceptor, the neutral radical (W48•) is formed. The lifetime of W48• in apoazurin is 41 s, which is shorter than the li...

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Detalles Bibliográficos
Autores principales: López-Peña, Ignacio, Lee, Christopher T., Rivera, Joel J., Kim, Judy E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9483921/
https://www.ncbi.nlm.nih.gov/pubmed/35977067
http://dx.doi.org/10.1021/acs.jpcb.2c02441

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9483921/
https://www.ncbi.nlm.nih.gov/pubmed/35977067
http://dx.doi.org/10.1021/acs.jpcb.2c02441

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