The Merger of Benzophenone HAT Photocatalysis and Silyl Radical-Induced XAT Enables Both Nickel-Catalyzed Cross-Electrophile Coupling and 1,2-Dicarbofunctionalization of Olefins

[Image: see text] A strategy for both cross-electrophile coupling and 1,2-dicarbofunctionalization of olefins has been developed. Carbon-centered radicals are generated from alkyl bromides by merging benzophenone hydrogen atom transfer (HAT) photocatalysis and silyl radical-induced halogen atom tran...

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Detalles Bibliográficos
Autores principales: Luridiana, Alberto, Mazzarella, Daniele, Capaldo, Luca, Rincón, Juan A., García-Losada, Pablo, Mateos, Carlos, Frederick, Michael O., Nuño, Manuel, Jan Buma, Wybren, Noël, Timothy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9486949/
https://www.ncbi.nlm.nih.gov/pubmed/36158902
http://dx.doi.org/10.1021/acscatal.2c03805

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