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Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution
The sorption removal of radionuclides Sr(2+) using a freestanding functional membrane is an interesting and significant research area in the remediation of radioactive wastes. Herein, a novel self-assembled membrane consisting of metal–organic framework (MOF) nanobelts and graphene oxides (GOs) are...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9488098/ https://www.ncbi.nlm.nih.gov/pubmed/36159605 http://dx.doi.org/10.1016/j.ese.2020.100035 |
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author | Cheng, Junye Liu, Kaili Li, Xin Huang, Lei Liang, Jie Zheng, Guangping Shan, Guangcun |
author_facet | Cheng, Junye Liu, Kaili Li, Xin Huang, Lei Liang, Jie Zheng, Guangping Shan, Guangcun |
author_sort | Cheng, Junye |
collection | PubMed |
description | The sorption removal of radionuclides Sr(2+) using a freestanding functional membrane is an interesting and significant research area in the remediation of radioactive wastes. Herein, a novel self-assembled membrane consisting of metal–organic framework (MOF) nanobelts and graphene oxides (GOs) are synthesized through a simple and facile filtration method. The membrane possesses a unique interwove morphology as evidenced from SEM images. Batch experiments suggest that the GO/Ni-MOF composite membrane could remove Sr(2+) ions from aqueous solutions and the Sr(2+) adsorption capacity and efficiency of the GO/Ni-MOF composite membrane is relevant to the MOF content in the composite. Thus, the dominant interaction mechanism was interface or surface complexation, electrostatic interaction as well as ion substitution. The maximum effective sorption of Sr(2+) over GO/Ni-MOF membrane is 32.99% with 2 mg composite membrane containing a high content of Ni-MOF at 299 K in 100 mg/L Sr(2+) aqueous solution. The FT-IR and XPS results suggest that the synergistic effect between GO and Ni-MOF is determinant in the sorption Sr(2+) process. The GO/Ni-MOF composite membrane is demonstrated to have the advantages of efficient removal of Sr(2+), low cost and simple synthesis route, which is promising in the elimination of radionuclide contamination. |
format | Online Article Text |
id | pubmed-9488098 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-94880982022-09-23 Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution Cheng, Junye Liu, Kaili Li, Xin Huang, Lei Liang, Jie Zheng, Guangping Shan, Guangcun Environ Sci Ecotechnol Original Research The sorption removal of radionuclides Sr(2+) using a freestanding functional membrane is an interesting and significant research area in the remediation of radioactive wastes. Herein, a novel self-assembled membrane consisting of metal–organic framework (MOF) nanobelts and graphene oxides (GOs) are synthesized through a simple and facile filtration method. The membrane possesses a unique interwove morphology as evidenced from SEM images. Batch experiments suggest that the GO/Ni-MOF composite membrane could remove Sr(2+) ions from aqueous solutions and the Sr(2+) adsorption capacity and efficiency of the GO/Ni-MOF composite membrane is relevant to the MOF content in the composite. Thus, the dominant interaction mechanism was interface or surface complexation, electrostatic interaction as well as ion substitution. The maximum effective sorption of Sr(2+) over GO/Ni-MOF membrane is 32.99% with 2 mg composite membrane containing a high content of Ni-MOF at 299 K in 100 mg/L Sr(2+) aqueous solution. The FT-IR and XPS results suggest that the synergistic effect between GO and Ni-MOF is determinant in the sorption Sr(2+) process. The GO/Ni-MOF composite membrane is demonstrated to have the advantages of efficient removal of Sr(2+), low cost and simple synthesis route, which is promising in the elimination of radionuclide contamination. Elsevier 2020-06-12 /pmc/articles/PMC9488098/ /pubmed/36159605 http://dx.doi.org/10.1016/j.ese.2020.100035 Text en © 2020 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Original Research Cheng, Junye Liu, Kaili Li, Xin Huang, Lei Liang, Jie Zheng, Guangping Shan, Guangcun Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution |
title | Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution |
title_full | Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution |
title_fullStr | Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution |
title_full_unstemmed | Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution |
title_short | Nickel-metal-organic framework nanobelt based composite membranes for efficient Sr(2+) removal from aqueous solution |
title_sort | nickel-metal-organic framework nanobelt based composite membranes for efficient sr(2+) removal from aqueous solution |
topic | Original Research |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9488098/ https://www.ncbi.nlm.nih.gov/pubmed/36159605 http://dx.doi.org/10.1016/j.ese.2020.100035 |
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