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(NHC)Pd(II) hydride-catalyzed dehydroaromatization by olefin chain-walking isomerization and transfer-dehydrogenation
Transition-metal-catalyzed homogeneous dehydrogenation and isomerization are common organic molecular activation reactions. Palladium hydrides are good olefin isomerization catalysts but are usually short-lived species under redox-active dehydrogenation conditions. Here, we show that Pd-H in the pre...
Autores principales: | Chen, Weihao, Chen, Yang, Gu, Xiao, Chen, Zaizhu, Ho, Chun-Yu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9489721/ https://www.ncbi.nlm.nih.gov/pubmed/36127352 http://dx.doi.org/10.1038/s41467-022-33163-6 |
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